金属密封剂增加通量并改变支持熔盐膜的选择性。

IF 3.4 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Reaction Chemistry & Engineering Pub Date : 2024-12-03 DOI:10.1039/D4RE00449C
Liam A. McNeil, Guannan Chen, Wenting Hu, Evangelos I. Papaioannou, Ian S. Metcalfe and Greg A. Mutch
{"title":"金属密封剂增加通量并改变支持熔盐膜的选择性。","authors":"Liam A. McNeil, Guannan Chen, Wenting Hu, Evangelos I. Papaioannou, Ian S. Metcalfe and Greg A. Mutch","doi":"10.1039/D4RE00449C","DOIUrl":null,"url":null,"abstract":"<p >Metallic sealants are widely used with high-temperature membranes. Here we show that their use in supported molten-salt membranes results in order-of-magnitude differences in CO<small><sub>2</sub></small> flux and introduces O<small><sub>2</sub></small> co-permeation. The ‘short-circuiting’ effect they introduce has important implications for the design of future experiments, and the interpretation of past work.</p>","PeriodicalId":101,"journal":{"name":"Reaction Chemistry & Engineering","volume":" 2","pages":" 294-299"},"PeriodicalIF":3.4000,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11632589/pdf/","citationCount":"0","resultStr":"{\"title\":\"Metallic sealants increase flux and change selectivity in supported molten-salt membranes\",\"authors\":\"Liam A. McNeil, Guannan Chen, Wenting Hu, Evangelos I. Papaioannou, Ian S. Metcalfe and Greg A. Mutch\",\"doi\":\"10.1039/D4RE00449C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Metallic sealants are widely used with high-temperature membranes. Here we show that their use in supported molten-salt membranes results in order-of-magnitude differences in CO<small><sub>2</sub></small> flux and introduces O<small><sub>2</sub></small> co-permeation. The ‘short-circuiting’ effect they introduce has important implications for the design of future experiments, and the interpretation of past work.</p>\",\"PeriodicalId\":101,\"journal\":{\"name\":\"Reaction Chemistry & Engineering\",\"volume\":\" 2\",\"pages\":\" 294-299\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-12-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11632589/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reaction Chemistry & Engineering\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/re/d4re00449c\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reaction Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/re/d4re00449c","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

金属密封剂广泛用于高温膜。在这里,我们展示了在支撑熔盐膜中使用金属密封剂会导致二氧化碳通量的数量级差异,并引入氧气共渗。它们引入的 "短路 "效应对未来实验的设计和过去工作的解释具有重要影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Metallic sealants increase flux and change selectivity in supported molten-salt membranes

Metallic sealants are widely used with high-temperature membranes. Here we show that their use in supported molten-salt membranes results in order-of-magnitude differences in CO2 flux and introduces O2 co-permeation. The ‘short-circuiting’ effect they introduce has important implications for the design of future experiments, and the interpretation of past work.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Reaction Chemistry & Engineering
Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)
CiteScore
6.60
自引率
7.70%
发文量
227
期刊介绍: Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.
期刊最新文献
Back cover Correction: Intensification of silver nanoparticle synthesis through continuous flow split and recombine microreactors Correction: Rare-earth doped hexagonal NaYbF4 nanoprobes with size-controlled and NIR-II emission for multifunctional applications Back cover Self-optimising continuous-flow hydrothermal reactor for nanoparticle synthesis†
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1