二芳基germanesione和二芳基germaneselone的合成与表征

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR European Journal of Inorganic Chemistry Pub Date : 2024-09-30 DOI:10.1002/ejic.202400390

Yizhen Chen, Gengwen Tan

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引用次数: 0

摘要

以杂性二芳基锗烯为原料，分别与单质硫和硒反应合成了无Lewis酸/碱的二芳基germanesione 3和二芳基germaneselone 4。通过结构、光谱和计算方法对它们进行了充分的表征。Germanethione与AlMe3在Ge=S双键处进行1,2加成得到Ge（IV）化合物5。3和4中的硫原子可以与卤化铜配位，分别生成Cu(I)配合物6和7。

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Synthesis and Characterization of Diarylgermanethione and Diarylgermaneselenone

Lewis acid/base-free diarylgermanethione 3 and diarylgermaneselenone 4 were synthesized through reactions of a heteroleptic diarylgermylene with elemental sulfur and selenium, respectively. They were fully characterized by structural, spectroscopic and computational methods. Germanethione underwent 1,2-addition with AlMe₃ at the Ge=S double to give Ge(IV) compound 5. The chalcogen atoms in 3 and 4 could coordinate to copper halide to yield Cu(I) complexes 6 and 7, respectively.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.