甲基2 - [(Z) 5-methyl-2-oxoindolin-3-yl-idene] hydrazinecarbodi-thio-ate。

IUCrData Pub Date : 2024-10-08 eCollection Date: 2024-10-01 DOI:10.1107/S2414314624009672

Mohd Abdul Fatah Abdul Manan, David B Cordes, Aidan P McKay

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摘要

由s -甲基-二硫代氨基甲酸酯（SMDTC）与5-甲基化isatin缩合反应得到标题为C11H11N3OS2的氨基甲酸二硫代氨基甲酸亚胺。它显示了亚胺C=N键的Z构型，该键与分子内的N- h⋯O氢键相关联，该氢键闭合S(6)环。在晶体中，由成对的N-H⋯O氢键连接的倒置二聚体产生r22(8)环。扩展结构具有C- h⋯S接触以及相互作用的碳-基-羰基（C=O⋯C=O）相互作用。

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Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-yl-idene]hydrazinecarbodi-thio-ate.

The title di-thio-carbazate imine, C₁₁H₁₁N₃OS₂, was obtained from the condensation reaction of S-methyl-dithio-carbazate (SMDTC) and 5-methyl-isatin. It shows a Z configuration about the imine C=N bond, which is associated with an intra-molecular N-H⋯O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N-H⋯O hydrogen bonds generate R ² ₂(8) loops. The extended structure features C-H⋯S contacts as well as reciprocal carbon-yl-carbonyl (C=O⋯C=O) inter-actions.