{"title":"卤素对3,4,5,6-四氯邻苯二甲酸盐系镧系配位化合物晶体填充的影响","authors":"Fallou Ngom, Chloé Blais, Insa Badiane, Christine Hénaff, Magatte Camara, Carole Daiguebonne and Olivier Guillou","doi":"10.1039/D4CE00966E","DOIUrl":null,"url":null,"abstract":"<p >Crystal growth in water between lanthanide ions and tetra-chloro-benzene-1,2-di-carboxylate (tcpa<small><sup>2−</sup></small>) led to 6 new coordination compounds with respective chemical formulas [Y(tcpa)(OH)(H<small><sub>2</sub></small>O)<small><sub>3</sub></small>]<small><sub>∞</sub></small> (<strong>1</strong>), Nd<small><sub>4</sub></small>(tcpa)<small><sub>6</sub></small>(H<small><sub>2</sub></small>O)<small><sub>22</sub></small>·8H<small><sub>2</sub></small>O (<strong>2</strong>), [KLa(tcpa)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>10</sub></small>·H<small><sub>2</sub></small>O]<small><sub>∞</sub></small> (<strong>3</strong>), [KLa(tcpa)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>5</sub></small>·2H<small><sub>2</sub></small>O]<small><sub>∞</sub></small> (<strong>4</strong>), Y(tcpa)(Htcpa)(H<small><sub>2</sub></small>O)<small><sub>5</sub></small> (<strong>5</strong>) and [KTb(tcpa)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>6</sub></small>·H<small><sub>2</sub></small>O]<small><sub>∞</sub></small> (<strong>6</strong>). The crystal structures of these six compounds are described and compared with previously described crystal structures, focusing on the structural characteristics that are known for being key points for luminescence intensity. Trends induced by the presence of halogen atoms are identified.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 2","pages":" 210-225"},"PeriodicalIF":2.6000,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of halogens on the crystal packing of 3,4,5,6-tetra-chloro-phthalate-based lanthanide coordination compounds†\",\"authors\":\"Fallou Ngom, Chloé Blais, Insa Badiane, Christine Hénaff, Magatte Camara, Carole Daiguebonne and Olivier Guillou\",\"doi\":\"10.1039/D4CE00966E\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Crystal growth in water between lanthanide ions and tetra-chloro-benzene-1,2-di-carboxylate (tcpa<small><sup>2−</sup></small>) led to 6 new coordination compounds with respective chemical formulas [Y(tcpa)(OH)(H<small><sub>2</sub></small>O)<small><sub>3</sub></small>]<small><sub>∞</sub></small> (<strong>1</strong>), Nd<small><sub>4</sub></small>(tcpa)<small><sub>6</sub></small>(H<small><sub>2</sub></small>O)<small><sub>22</sub></small>·8H<small><sub>2</sub></small>O (<strong>2</strong>), [KLa(tcpa)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>10</sub></small>·H<small><sub>2</sub></small>O]<small><sub>∞</sub></small> (<strong>3</strong>), [KLa(tcpa)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>5</sub></small>·2H<small><sub>2</sub></small>O]<small><sub>∞</sub></small> (<strong>4</strong>), Y(tcpa)(Htcpa)(H<small><sub>2</sub></small>O)<small><sub>5</sub></small> (<strong>5</strong>) and [KTb(tcpa)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>6</sub></small>·H<small><sub>2</sub></small>O]<small><sub>∞</sub></small> (<strong>6</strong>). The crystal structures of these six compounds are described and compared with previously described crystal structures, focusing on the structural characteristics that are known for being key points for luminescence intensity. Trends induced by the presence of halogen atoms are identified.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 2\",\"pages\":\" 210-225\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-12-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d4ce00966e\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d4ce00966e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Influence of halogens on the crystal packing of 3,4,5,6-tetra-chloro-phthalate-based lanthanide coordination compounds†
Crystal growth in water between lanthanide ions and tetra-chloro-benzene-1,2-di-carboxylate (tcpa2−) led to 6 new coordination compounds with respective chemical formulas [Y(tcpa)(OH)(H2O)3]∞ (1), Nd4(tcpa)6(H2O)22·8H2O (2), [KLa(tcpa)2(H2O)10·H2O]∞ (3), [KLa(tcpa)2(H2O)5·2H2O]∞ (4), Y(tcpa)(Htcpa)(H2O)5 (5) and [KTb(tcpa)2(H2O)6·H2O]∞ (6). The crystal structures of these six compounds are described and compared with previously described crystal structures, focusing on the structural characteristics that are known for being key points for luminescence intensity. Trends induced by the presence of halogen atoms are identified.
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