D Gheorghe, A Neacsu, A Sofronia, C Marinescu, S Perisanu
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Thermodynamic study of anhydrous and hydrated quercetin
Solid-state anhydrous (QA) and hydrated quercetins (QH) were studied by using combustion calorimetry and thermal analysis-simultaneous thermogravimetry (TG) coupled with differential scanning calorimetry (DSC) methods. The enthalpies of formation were derived employing the experimental heat of combustion for the studied compounds. The obtained data are compared with estimated values using group additivity and quantum calculations. The correlation between experimental and calculated values is discussed considering the number and strength of intermolecular hydrogen bonds. From DSC experiments, the temperature ranges of dehydration followed by melting-decomposition were established.
Graphical abstract
The present study consists in bringing contributions to the completion of thermochemical data banks regarding the important role played by quercetin in the living organisms. The values of the thermodynamic quantities, which characterize the biochemical reactions, are put in correspondence with the biological activity of quercetin.
Synopsis The present study consists in bringing contributions to the completion of thermochemical data banks regarding the important role played by quercetin in the living organisms. The values of the thermodynamic quantities, which characterize the biochemical reactions, are put in correspondence with the biological activity of quercetin.
期刊介绍：
Journal of Chemical Sciences is a monthly journal published by the Indian Academy of Sciences. It formed part of the original Proceedings of the Indian Academy of Sciences – Part A, started by the Nobel Laureate Prof C V Raman in 1934, that was split in 1978 into three separate journals. It was renamed as Journal of Chemical Sciences in 2004. The journal publishes original research articles and rapid communications, covering all areas of chemical sciences. A significant feature of the journal is its special issues, brought out from time to time, devoted to conference symposia/proceedings in frontier areas of the subject, held not only in India but also in other countries.
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