关注微孔钙钛矿：老狗的新把戏

IF 7.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical Science Pub Date : 2025-01-06 DOI:10.1039/D4SC90244K

Miriam Segundo-Osorio, A. Paulina Gómora-Figueroa and Diego Solis-Ibarra

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引用次数: 0

摘要

杂化有机-无机钙钛矿（HOIPs）由于其独特的半导体特性而在光电器件中具有广泛的应用前景。多孔hoip极为罕见，（APOSS）[CuCl4]4是为数不多的例子之一，其晶格内有12个Å孔。里德和他的同事(C. W.道尔顿，P. M.甘农，W.卡明斯基和D. A.里德，化学。科学。， 2025, DOI: https://doi.org/10.1039/D4SC04378B)最近揭示了这种有趣材料的结构，并证明这些孔隙可以结合大的电活性分子，如二茂铁（Fc）和四氰乙烯（TCNE）。此外，他们还表明，在孔隙中加入分子的能力也可以合成新的晶体相，并解锁许多应用，包括气体传感和光催化等。

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A focus on microporous perovskites: new tricks for an old dog

Hybrid organic–inorganic perovskites (HOIPs) are widely studied for their potential in optoelectronic devices due to their unique semiconductor features. Porous HOIPs are extremely rare, with (APOSS)[CuCl₄]₄ being one of the very few examples, featuring 12 Å pores within its lattice. Reed and coworkers (C. W. Dalton, P. M. Gannon, W. Kaminsky and D. A. Reed, Chem. Sci., 2025, DOI: https://doi.org/10.1039/D4SC04378B) have recently shed light on the structure of this interesting material and demonstrated that these pores can incorporate large electroactive molecules such as ferrocene (Fc) and tetracyanoethylene (TCNE). Further, they showed that the ability to incorporate molecules within the pores also enables the synthesis of new crystalline phases and unlocks numerous applications, including gas sensing and photocatalysis, among others.

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来源期刊

Chemical Science CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

14.40

自引率

4.80%

发文量

1352

审稿时长

2.1 months

期刊介绍： Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.