基于fe掺杂NiO纳米结构的选择性检测三乙胺和二甲苯气体传感器

IF 2.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY New Journal of Chemistry Pub Date : 2024-12-05 DOI:10.1039/D4NJ04799K
Qi Zhao, Siqi Yang, Zihan Liu, Yuan You and Dongxue Wang
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引用次数: 0

摘要

三乙胺和二甲苯等有害气体的实时检测对人类和环境安全具有重要意义。本文合成了不同掺杂浓度的Fe-NiO纳米结构。掺入Fe后,NiO纳米结构的气敏性显著提高。气敏性能测试结果表明,0.93 at% Fe-NiO纳米结构传感器在TEA和二甲苯检测方面具有更大的潜力。基于0.93 at% Fe-NiO纳米结构的传感器在220°C的工作温度下显示出38-50 ppm TEA和18-50 ppm二甲苯的最高响应值。此外,该传感器还具有良好的选择性、稳定性和可重复性。传感特性的增强可归因于Fe掺杂了更多的氧空位。所制备的Fe-NiO纳米结构为TEA和二甲苯的双选择性检测提供了一种新的方法。并对其传感机理进行了研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Fe-doped NiO nanostructure-based gas sensor for selective detection of triethylamine and xylene

The real-time detection of noxious gases such as triethylamine (TEA) and xylene is important for human and environmental safety. In this work, Fe–NiO nanostructures with different doping concentrations were synthesized. By doping Fe, the gas sensitivity of NiO nanostructures was significantly improved. Gas-sensitive performance test results show that 0.93 at% Fe–NiO nanostructure-based sensors have more potential for TEA and xylene detection. The 0.93 at% Fe–NiO nanostructure-based sensor displays the highest response value of 38–50 ppm TEA at a working temperature of 220 °C and 18–50 ppm xylene at an operating temperature of 250 °C. Furthermore, the sensors show outstanding selectivity, stability and repeatability. The enhanced sensing characteristics can be ascribed to the doping of Fe with more oxygen vacancies. The as-prepared Fe–NiO nanostructures provide a novel dual-selectivity method for detection of TEA and xylene. In addition, the sensing mechanism was studied.

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来源期刊
New Journal of Chemistry
New Journal of Chemistry 化学-化学综合
CiteScore
5.30
自引率
6.10%
发文量
1832
审稿时长
2 months
期刊介绍: A journal for new directions in chemistry
期刊最新文献
Back cover Back cover Development and validation of a high-throughput HPLC-MS/MS method for the simultaneous determination of exatecan and its cathepsin B-sensitive prodrug in rat plasma† A bimetallic catalyst of Fe–Co nanocomposite encapsulated in N-doped carbon nanotubes for colorimetric monitoring and degradation of hydroquinone in rivers† Impact of coordinated nitrogen atoms on the electrocatalytic water oxidation properties of copper complexes with pentadentate ligands†
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