Ting Ouyang, Xinyu Wang, Huilin Lan, Luoqi Liu, Ying Bai, Jiayun Li and Jiajian Peng
{"title":"海泡石负载甲酸铜作为烯烃硅氢化反应的可重复使用催化剂","authors":"Ting Ouyang, Xinyu Wang, Huilin Lan, Luoqi Liu, Ying Bai, Jiayun Li and Jiajian Peng","doi":"10.1039/D4NJ04379K","DOIUrl":null,"url":null,"abstract":"<p >Sepiolite, an abundant and environmentally friendly natural mineral, has been widely used as a catalyst support. Copper formate supported on sepiolite was prepared. The Cu(HCOO)<small><sub>2</sub></small>/sepiolite catalyst showed high catalytic activity and selectivity in the anti-Markovnikov hydrosilylation of various olefins under mild conditions. Notably, the Cu(HCOO)<small><sub>2</sub></small>/sepiolite catalyst exhibited remarkable reusability, maintaining its catalytic performance over at least 16 times.</p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":" 3","pages":" 679-682"},"PeriodicalIF":2.5000,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Copper formate supported on sepiolite as a reusable catalyst for the hydrosilylation of olefins†\",\"authors\":\"Ting Ouyang, Xinyu Wang, Huilin Lan, Luoqi Liu, Ying Bai, Jiayun Li and Jiajian Peng\",\"doi\":\"10.1039/D4NJ04379K\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Sepiolite, an abundant and environmentally friendly natural mineral, has been widely used as a catalyst support. Copper formate supported on sepiolite was prepared. The Cu(HCOO)<small><sub>2</sub></small>/sepiolite catalyst showed high catalytic activity and selectivity in the anti-Markovnikov hydrosilylation of various olefins under mild conditions. Notably, the Cu(HCOO)<small><sub>2</sub></small>/sepiolite catalyst exhibited remarkable reusability, maintaining its catalytic performance over at least 16 times.</p>\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":\" 3\",\"pages\":\" 679-682\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-12-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/nj/d4nj04379k\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/nj/d4nj04379k","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Copper formate supported on sepiolite as a reusable catalyst for the hydrosilylation of olefins†
Sepiolite, an abundant and environmentally friendly natural mineral, has been widely used as a catalyst support. Copper formate supported on sepiolite was prepared. The Cu(HCOO)2/sepiolite catalyst showed high catalytic activity and selectivity in the anti-Markovnikov hydrosilylation of various olefins under mild conditions. Notably, the Cu(HCOO)2/sepiolite catalyst exhibited remarkable reusability, maintaining its catalytic performance over at least 16 times.