Direct Synthesis of Polyethylene Containing Two Kinds of Heteroatoms by Scandium Complexes

Polar polyolefins are of fundamental interest and practical significance. The direct synthesis of polyethylene containing two kinds of heteroatoms by early transition catalysts is still rare due to the complicated poisoning action, but these novel copolymers may behave superposed and unexpected characteristic. Herein we report the production of polyethylene containing two distinct polar groups (such as O, S and F) by scandium complexes. Sc-2 with bulkier ligand can raise polar olefin incorporation. S and F atoms on comonomer 1g (2S/F-o) shows significantly positive effect during copolymerization with ethylene and results in high incorporation ratio (17.2 to 44.9 mol%), high activity (69.0 to 211 kg mol_Sc^–1 h^–1 bar^–1) and high molecular weight (Mn) up to 33.3 × 10⁴ g mol^–1. The polymerization mechanistic aspect of cooperative action between S and F atoms on 1g has been elucidated by DFT studies. We expect that our new findings could guide the synthesis of polyolefins containing multi-functional groups.