pt -纳米颗粒负载多孔SnO2优化室温下h2s传感性能

IF 6.3 Q1 ENGINEERING, ENVIRONMENTAL ACS ES&T engineering Pub Date : 2024-11-19 DOI:10.1021/acsestengg.4c00522
Peijin Zou, Zhuangzhuang Ma, Zihuan Tang, Xiaotong Gao, Xiaoxiong Hou and Lichao Jia*, 
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引用次数: 0

摘要

实现基于金属氧化物半导体(MOS)气体传感器对硫化氢(H2S)的实时检测,对疾病的快速诊断具有重要意义。但其功耗高、选择性差严重限制了其实际应用。在本研究中,成功合成了一种负载铂纳米粒子(Pt NPs)的多孔金属有机骨架(MOF)衍生的SnO2材料,以优化其在室温下的h2s传感性能。优化后的铂负载多孔sno2基气体传感器在室温下对H2S (10 ppb)的检测限极低,灵敏度高(712-10 ppm),响应速度快(21 s),选择性好。深入分析表明,Sn-MOF的多孔结构可以为气体分子提供足够的活性反应位点。此外,表面负载Pt NPs的均匀分布可以引发电子和化学增敏效应,从而提高传感性能。Pt纳米粒子的成功应用为提高金属氧化物半导体气体传感器的室温(RT)传感性能提供了一种新的方法。
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Pt-Nanoparticle-Loaded Porous SnO2 for Optimizing H2S-Sensing Performance at Room Temperature

Achieving the real-time detection of hydrogen sulfide (H2S) based on metal oxide semiconductor (MOS) gas sensors is of great significance for rapid disease diagnosis. However, the high-power consumption and poor selectivity severely limit its practice application. In this study, a platinum nanoparticle (Pt NPs)-loaded porous metal–organic framework (MOF)-derived SnO2 material was successfully synthesized to optimize the H2S-sensing performance at room temperature. The optimized Pt-loaded porous SnO2-based gas sensor exhibited remarkably high sensitivity (712–10 ppm), fast response (21 s), good selectivity, and extremely low detection limit for H2S (10 ppb) at room temperature. The in-depth analysis demonstrated that the porous structure of Sn-MOF can provide adequate active reaction sites for gas molecules. Moreover, the uniform distribution of surface-loaded Pt NPs can initiate electron and chemical sensitization effects, thereby improving the sensing performance. The successful application of Pt NPs provides a novel approach to improve the room-temperature (RT) sensing performance of metal-oxide-semiconductor-based gas sensors.

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来源期刊
ACS ES&T engineering
ACS ES&T engineering ENGINEERING, ENVIRONMENTAL-
CiteScore
8.50
自引率
0.00%
发文量
0
期刊介绍: ACS ES&T Engineering publishes impactful research and review articles across all realms of environmental technology and engineering, employing a rigorous peer-review process. As a specialized journal, it aims to provide an international platform for research and innovation, inviting contributions on materials technologies, processes, data analytics, and engineering systems that can effectively manage, protect, and remediate air, water, and soil quality, as well as treat wastes and recover resources. The journal encourages research that supports informed decision-making within complex engineered systems and is grounded in mechanistic science and analytics, describing intricate environmental engineering systems. It considers papers presenting novel advancements, spanning from laboratory discovery to field-based application. However, case or demonstration studies lacking significant scientific advancements and technological innovations are not within its scope. Contributions containing experimental and/or theoretical methods, rooted in engineering principles and integrated with knowledge from other disciplines, are welcomed.
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