氧化石墨烯集成CeMnO3复合材料在高效电化学过程中的应用

IF 4.9 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Journal of Physics and Chemistry of Solids Pub Date : 2025-05-01 Epub Date: 2025-01-20 DOI:10.1016/j.jpcs.2025.112576
Taghrid S. Alomar , Najla AlMasoud , Mahmood Ali , Amal A. Al-wallan , Hafiz Muhammad Tahir , Zeinhom M. El-Bahy
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引用次数: 0

摘要

能量转换和存储技术目前受到广泛关注,因为它们为日益严重的能源问题提供了解决方案。本文报道了用水热法制备CeMnO3/GO纳米复合材料。物理分析和电化学分析采用了不同的分析策略。在电流密度为1 A/g时,复合材料的电容(Cs)值为1106 F/g,比能量(SE)为62 Wh/Kg,比功率(SP)为315 W/ Kg,在循环3000次50 h后仍保持稳定。经CV分析,复合材料的过电位(η)为213 mV, Tafel斜率为36 mV/dec。在CeMnO3中加入氧化石墨烯,提高了界面面积,促进了更快的电荷传输,从而提高了电化学性能。奈奎斯特图显示,CeMnO3@GO纳米复合材料的电荷转移阻值较小,为0.87 Ω。这种材料非凡的稳定性表明,它有潜力储存超级电容器的能量。
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Application of GO-integrated CeMnO3 composite for high-efficiency electrochemical process
Energy conversion and storage technologies are currently receiving a lot of attention because they offer solution for growing energy problems. The present work reported on the fabrication of CeMnO3/GO nanocomposite through a hydrothermal method. Different analytical strategies have been employed for the physical and electrochemical analysis. The capacitance (Cs) values of prepared composite were 1106 F/g with specific energy (SE) 62 Wh/Kg and specific power (SP) 315 W/kg at current density 1 A/g which showed stability even after 3000th cycle for 50 h. The synthesized CeMnO3/GO composite possessed overpotentials (η) of 213 mV and Tafel slope value of 36 mV/dec determined from CV analysis for water splitting studies. The addition of graphene oxide to CeMnO3, improves interfacial area and facilitates faster charge transport which results improvement in electrochemical performance. The Nyquist plot examines smaller charge transfer resistance value of 0.87 Ω for CeMnO3@GO nanocomposite. The material's remarkable stability suggested its potential for storing energy for supercapacitor applications.
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来源期刊
Journal of Physics and Chemistry of Solids
Journal of Physics and Chemistry of Solids 工程技术-化学综合
CiteScore
7.80
自引率
2.50%
发文量
605
审稿时长
40 days
期刊介绍: The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems. Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal: Low-dimensional systems Exotic states of quantum electron matter including topological phases Energy conversion and storage Interfaces, nanoparticles and catalysts.
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