Wei-Hao Chen, Yen-Hsin Chen, Kedar Bahadur Thapa, Shih-Miao Liu and Jhy-Der Chen
{"title":"由二吡啶-二酰胺和1,4,5,8-萘四羧酸构建的配位聚合物：配体转化和金属离子传感†","authors":"Wei-Hao Chen, Yen-Hsin Chen, Kedar Bahadur Thapa, Shih-Miao Liu and Jhy-Der Chen","doi":"10.1039/D4CE01119H","DOIUrl":null,"url":null,"abstract":"<p >Hydrothermal reactions of 1,4,5,8-naphthalenetetracarboxylic acid (1,4,5,8-H<small><sub>4</sub></small>NTC) with various bis-pyridyl-bis-amides, <em>N</em>,<em>N</em>′-di(pyridin-3-yl)adipamide (<strong>L</strong><small><sup><strong>1</strong></sup></small>), <em>N</em>,<em>N</em>′-di(pyridin-3-yl)succinamide (<strong>L</strong><small><sup><strong>2</strong></sup></small>), <em>N</em>,<em>N</em>′-di(pyridin-3-yl)oxalamide (<strong>L</strong><small><sup><strong>3</strong></sup></small>) or <em>N</em>,<em>N</em>′-bis(pyridin-3-ylmethyl)oxalamide (<strong>L</strong><small><sup><strong>4</strong></sup></small>) and transition metal salt afforded seven coordination polymers (CPs) and one dinuclear complex, including [Cd(<strong>L</strong><small><sup><strong>1</strong></sup></small>)<small><sub>0.5</sub></small>(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)<small><sub>2</sub></small>]<small><sub><em>n</em></sub></small> (1,4,5,8-H<small><sub>2</sub></small>NTC′ = 1,4,5,8-naphthalenetetracarboxylic acid 1,8-monoanhydride), <strong>1</strong>, {[Zn(<strong>L</strong><small><sup><strong>2</strong></sup></small>)<small><sub>0.5</sub></small>(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)<small><sub>2</sub></small>]·H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small>, <strong>2</strong>, {[Cd(<strong>L</strong><small><sup><strong>2</strong></sup></small>)<small><sub>0.5</sub></small>(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)<small><sub>2</sub></small>]·H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small>, <strong>3</strong>, {[Zn(<strong>L</strong><small><sup><strong>5</strong></sup></small>)(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)]·0.5OA}<small><sub><em>n</em></sub></small>, {<strong>L</strong><small><sup><strong>5</strong></sup></small> = 2,7-di(pyridin-3-yl)benzo[<em>lmn</em>][3,8]phenanthroline-1,3,6,8(2<em>H</em>,7<em>H</em>)-tetraone}, <strong>4</strong>, [Cd(<strong>L</strong><small><sup><strong>5</strong></sup></small>)(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)]<small><sub><em>n</em></sub></small>, <strong>5a</strong>, {[Cd(<strong>L</strong><small><sup><strong>5</strong></sup></small>)(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)]·2H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small>, <strong>5b</strong>, [Zn<small><sub>2</sub></small>(<strong>L</strong><small><sup><strong>4</strong></sup></small>)(1,4,5,8-NTC′)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>6</sub></small>], <strong>6</strong>, and {[Cd(<strong>L</strong><small><sup><strong>4</strong></sup></small>)(1,4,5,8-NTC)<small><sub>0.5</sub></small>(H<small><sub>2</sub></small>O)]·0.5H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small> (1,4,5,8-H<small><sub>4</sub></small>NTC = 1,4,5,8-naphthalenetetracarboxylic acid), <strong>7</strong>. These CPs and the dinuclear complex were structurally characterized by using X-ray single-crystal diffraction. CPs <strong>1</strong>, <strong>2</strong>, and <strong>3</strong> exhibit one-dimensional (1D) structures with the 2,3C2 topology and <strong>4</strong> and <strong>5</strong> display two-dimensional (2D) structures with the 2,4L1 topology, whereas <strong>6</strong> is a dinuclear complex and <strong>7</strong> shows a three-dimensional (3D) framework with the <strong>mog</strong> topology. Ligand transformations from 1,4,5,8-H<small><sub>4</sub></small>NTC to 1,4,5,8-NTC′<small><sup>2−</sup></small> and <strong>L</strong><small><sup><strong>3</strong></sup></small> to <strong>L</strong><small><sup><strong>5</strong></sup></small> are observed. The evaluation of the metal ion sensing properties of <strong>1</strong>, <strong>2</strong>, <strong>3</strong>, <strong>6</strong>, and <strong>7</strong> shows that <strong>7</strong> has the highest potential for detecting Fe<small><sup>3+</sup></small> ions in aqueous solution with 1.06 × 10<small><sup>3</sup></small> M<small><sup>−1</sup></small> and 1.99 × 10<small><sup>−4</sup></small> M for the Stern–Volmer constant (<em>K</em><small><sub>SV</sub></small>) and the limit of detection (LOD), respectively.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 5","pages":" 606-615"},"PeriodicalIF":2.4000,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ce/d4ce01119h?page=search","citationCount":"0","resultStr":"{\"title\":\"Coordination polymers constructed from bis-pyridyl-bis-amides and 1,4,5,8-naphthalenetetracarboxylic acid: ligand transformation and metal ion sensing†\",\"authors\":\"Wei-Hao Chen, Yen-Hsin Chen, Kedar Bahadur Thapa, Shih-Miao Liu and Jhy-Der Chen\",\"doi\":\"10.1039/D4CE01119H\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Hydrothermal reactions of 1,4,5,8-naphthalenetetracarboxylic acid (1,4,5,8-H<small><sub>4</sub></small>NTC) with various bis-pyridyl-bis-amides, <em>N</em>,<em>N</em>′-di(pyridin-3-yl)adipamide (<strong>L</strong><small><sup><strong>1</strong></sup></small>), <em>N</em>,<em>N</em>′-di(pyridin-3-yl)succinamide (<strong>L</strong><small><sup><strong>2</strong></sup></small>), <em>N</em>,<em>N</em>′-di(pyridin-3-yl)oxalamide (<strong>L</strong><small><sup><strong>3</strong></sup></small>) or <em>N</em>,<em>N</em>′-bis(pyridin-3-ylmethyl)oxalamide (<strong>L</strong><small><sup><strong>4</strong></sup></small>) and transition metal salt afforded seven coordination polymers (CPs) and one dinuclear complex, including [Cd(<strong>L</strong><small><sup><strong>1</strong></sup></small>)<small><sub>0.5</sub></small>(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)<small><sub>2</sub></small>]<small><sub><em>n</em></sub></small> (1,4,5,8-H<small><sub>2</sub></small>NTC′ = 1,4,5,8-naphthalenetetracarboxylic acid 1,8-monoanhydride), <strong>1</strong>, {[Zn(<strong>L</strong><small><sup><strong>2</strong></sup></small>)<small><sub>0.5</sub></small>(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)<small><sub>2</sub></small>]·H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small>, <strong>2</strong>, {[Cd(<strong>L</strong><small><sup><strong>2</strong></sup></small>)<small><sub>0.5</sub></small>(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)<small><sub>2</sub></small>]·H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small>, <strong>3</strong>, {[Zn(<strong>L</strong><small><sup><strong>5</strong></sup></small>)(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)]·0.5OA}<small><sub><em>n</em></sub></small>, {<strong>L</strong><small><sup><strong>5</strong></sup></small> = 2,7-di(pyridin-3-yl)benzo[<em>lmn</em>][3,8]phenanthroline-1,3,6,8(2<em>H</em>,7<em>H</em>)-tetraone}, <strong>4</strong>, [Cd(<strong>L</strong><small><sup><strong>5</strong></sup></small>)(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)]<small><sub><em>n</em></sub></small>, <strong>5a</strong>, {[Cd(<strong>L</strong><small><sup><strong>5</strong></sup></small>)(1,4,5,8-NTC′)(H<small><sub>2</sub></small>O)]·2H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small>, <strong>5b</strong>, [Zn<small><sub>2</sub></small>(<strong>L</strong><small><sup><strong>4</strong></sup></small>)(1,4,5,8-NTC′)<small><sub>2</sub></small>(H<small><sub>2</sub></small>O)<small><sub>6</sub></small>], <strong>6</strong>, and {[Cd(<strong>L</strong><small><sup><strong>4</strong></sup></small>)(1,4,5,8-NTC)<small><sub>0.5</sub></small>(H<small><sub>2</sub></small>O)]·0.5H<small><sub>2</sub></small>O}<small><sub><em>n</em></sub></small> (1,4,5,8-H<small><sub>4</sub></small>NTC = 1,4,5,8-naphthalenetetracarboxylic acid), <strong>7</strong>. These CPs and the dinuclear complex were structurally characterized by using X-ray single-crystal diffraction. CPs <strong>1</strong>, <strong>2</strong>, and <strong>3</strong> exhibit one-dimensional (1D) structures with the 2,3C2 topology and <strong>4</strong> and <strong>5</strong> display two-dimensional (2D) structures with the 2,4L1 topology, whereas <strong>6</strong> is a dinuclear complex and <strong>7</strong> shows a three-dimensional (3D) framework with the <strong>mog</strong> topology. Ligand transformations from 1,4,5,8-H<small><sub>4</sub></small>NTC to 1,4,5,8-NTC′<small><sup>2−</sup></small> and <strong>L</strong><small><sup><strong>3</strong></sup></small> to <strong>L</strong><small><sup><strong>5</strong></sup></small> are observed. The evaluation of the metal ion sensing properties of <strong>1</strong>, <strong>2</strong>, <strong>3</strong>, <strong>6</strong>, and <strong>7</strong> shows that <strong>7</strong> has the highest potential for detecting Fe<small><sup>3+</sup></small> ions in aqueous solution with 1.06 × 10<small><sup>3</sup></small> M<small><sup>−1</sup></small> and 1.99 × 10<small><sup>−4</sup></small> M for the Stern–Volmer constant (<em>K</em><small><sub>SV</sub></small>) and the limit of detection (LOD), respectively.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 5\",\"pages\":\" 606-615\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-12-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/ce/d4ce01119h?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d4ce01119h\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d4ce01119h","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Coordination polymers constructed from bis-pyridyl-bis-amides and 1,4,5,8-naphthalenetetracarboxylic acid: ligand transformation and metal ion sensing†
Hydrothermal reactions of 1,4,5,8-naphthalenetetracarboxylic acid (1,4,5,8-H4NTC) with various bis-pyridyl-bis-amides, N,N′-di(pyridin-3-yl)adipamide (L1), N,N′-di(pyridin-3-yl)succinamide (L2), N,N′-di(pyridin-3-yl)oxalamide (L3) or N,N′-bis(pyridin-3-ylmethyl)oxalamide (L4) and transition metal salt afforded seven coordination polymers (CPs) and one dinuclear complex, including [Cd(L1)0.5(1,4,5,8-NTC′)(H2O)2]n (1,4,5,8-H2NTC′ = 1,4,5,8-naphthalenetetracarboxylic acid 1,8-monoanhydride), 1, {[Zn(L2)0.5(1,4,5,8-NTC′)(H2O)2]·H2O}n, 2, {[Cd(L2)0.5(1,4,5,8-NTC′)(H2O)2]·H2O}n, 3, {[Zn(L5)(1,4,5,8-NTC′)(H2O)]·0.5OA}n, {L5 = 2,7-di(pyridin-3-yl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone}, 4, [Cd(L5)(1,4,5,8-NTC′)(H2O)]n, 5a, {[Cd(L5)(1,4,5,8-NTC′)(H2O)]·2H2O}n, 5b, [Zn2(L4)(1,4,5,8-NTC′)2(H2O)6], 6, and {[Cd(L4)(1,4,5,8-NTC)0.5(H2O)]·0.5H2O}n (1,4,5,8-H4NTC = 1,4,5,8-naphthalenetetracarboxylic acid), 7. These CPs and the dinuclear complex were structurally characterized by using X-ray single-crystal diffraction. CPs 1, 2, and 3 exhibit one-dimensional (1D) structures with the 2,3C2 topology and 4 and 5 display two-dimensional (2D) structures with the 2,4L1 topology, whereas 6 is a dinuclear complex and 7 shows a three-dimensional (3D) framework with the mog topology. Ligand transformations from 1,4,5,8-H4NTC to 1,4,5,8-NTC′2− and L3 to L5 are observed. The evaluation of the metal ion sensing properties of 1, 2, 3, 6, and 7 shows that 7 has the highest potential for detecting Fe3+ ions in aqueous solution with 1.06 × 103 M−1 and 1.99 × 10−4 M for the Stern–Volmer constant (KSV) and the limit of detection (LOD), respectively.
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