高性能可见-红外宽带透明铜网导体及应用于电磁屏蔽和加热

IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Science China Materials Pub Date : 2025-01-02 DOI:10.1007/s40843-024-3186-7
Tengfei Li  (, ), Xiaolian Chen  (, ), Zhaohua Xu  (, ), Shuhong Nie  (, ), Wenya Xu  (, ), Wei Yuan  (, ), Su Xu  (, ), Shuo Zhang  (, ), Fangfang Pei  (, ), Wenming Su  (, ), Zheng Cui  (, )
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引用次数: 0

摘要

透明导体在现代光电探测器和智能窗等领域有着广泛的应用。虽然可见光波段的tc已经取得了重大进展,但由于红外透明度和导电性之间的权衡,可见光-红外(vis-IR)宽带红外tc的发展仍然是一个艰巨的挑战。本文提出了一种采用无损伤间接转移法制备的可见光红外热释光材料。该方法涉及通过转移膜将高分辨率的独立铜(Cu)网连接到红外或可见基片上的聚合物介导键合。所制得的铜网TC具有优异的导电性,片电阻低至0.06 Ω/□,在可见光波长550 nm处透光率为81%,红外波长10µm处透光率为65%。此外,专门开发的粘接策略确保了Cu网TC在恶劣环境中的长期可靠性。铜网TC既可用于加热屏蔽,也可用于电磁屏蔽。作为一种透明加热器,它在施加1.2 V的电压下在100秒内达到约100°C。在电磁屏蔽方面,使用一个带有透明观察窗口的不锈钢盒子进行演示,该窗口与铜网集成在一起,可以同时进行光学和红外观测,但盒子内智能手机的4G信号(8.2 GHz)被有效阻挡。
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High-performance visible-infrared broadband transparent copper mesh conductor and applications for electromagnetic shielding and heating

Transparent conductors (TCs) have widespread applications in the fields of modern photodetectors and smart windows. While TCs for visible wavelengths have seen significant advancements, the development of visible-infrared (vis-IR) broadband TCs for infrared is still a daunting challenge due to the trade-off between infrared transparency and conductivity. Here, we present a vis-IR TC fabricated by using a damage-free indirect transfer method. This method involves polymer-mediated bonding of a high-resolution, standalone copper (Cu) mesh onto infrared or visible substrates via a transfer film. The obtained Cu mesh TC exhibits excellent conductivity with a sheet resistance as low as 0.06 Ω/□, as well as 81% transmittance at a visible wavelength of 550 nm and 65% transmittance at an IR wavelength of 10 µm. Furthermore, a specially developed bonding strategy ensures the long-term reliability of the Cu mesh TC in harsh environments. The Cu mesh TC can be applied in both heating and electromagnetic (EM) shielding. As a transparent heater, it reaches approximately 100°C at an applied voltage of 1.2 V within 100 s. For EM shielding, a demonstration using a stainless-steel box with a transparent observation window which is integrated with the Cu mesh shows that while the window allows both optical and IR observations, the 4G signals (8.2 GHz) of a smartphone inside the box are effectively blocked.

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来源期刊
Science China Materials
Science China Materials Materials Science-General Materials Science
CiteScore
11.40
自引率
7.40%
发文量
949
期刊介绍: Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.
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