铝（III）催化成键反应

IF 1.8 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR European Journal of Inorganic Chemistry Pub Date : 2024-11-18 DOI:10.1002/ejic.202400638

Dipanjana Choudhury, Dominic S. Wright

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引用次数: 0

摘要

使用中性和阳离子Al（III）配合物的静态催化，金属的氧化态不改变，可以应用于一系列与过渡金属类似物具有相似特征的催化成键反应。这篇简短的综述（虽然不打算是全面的）强调了目前在脱氢偶联、烯烃聚合和其他涉及单位点Al（III）催化剂的成键反应领域的发展状况，特别关注分子活化和催化机制的关键因素。

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Catalytic Bond-Forming Reactions Using Aluminium(III)

Static catalysis using neutral and cationic Al(III) complexes, in which the oxidation state of the metal does not change, can be applied to a range of catalytic bond-forming reactions which have similar characteristics to transition metal analogues. This short review (although not intended to be comprehensive) highlights the current state of development in the areas of dehydrocoupling, alkene polymerisation, and other bond forming reactions involving single-site Al(III) catalysts, focusing in particular on the key factors involved in molecular activation and the mechanisms of catalysis.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.