{"title":"金属玻璃带前驱体中添加镍促进乙醇的电氧化。","authors":"Jingjing Song, Bo Zhang, Yu Chen, Qingzhuo Hu, Fabao Zhang, Langxiang Zhong","doi":"10.3390/ma18030701","DOIUrl":null,"url":null,"abstract":"<p><p>A CuNiCe-O nanocomposite was fabricated on the Cu<sub>40</sub>Ni<sub>20</sub>Al<sub>10</sub>Ce<sub>26</sub>Pt<sub>3</sub>Ru<sub>1</sub> metallic glass (MG) ribbon surface by dealloying. The influences of Ni and dealloying time on the morphology and EOR performance were analyzed. The results suggest that the catalytic activity and stability of the dealloyed MG ribbon could be significantly enhanced owing to the alloying of Ni to the Cu<sub>60</sub>Al<sub>10</sub>Ce<sub>26</sub>Pt<sub>3</sub>Ru<sub>1</sub> MG ribbon precursor. The activated D-Cu<sub>40</sub>Ni<sub>20</sub>Al<sub>10</sub>Ce<sub>26</sub>Pt<sub>3</sub>Ru<sub>1</sub> ribbon obtained at an etching time of 3 h had a better electrochemical ethanol oxidation reaction (EOR) performance than other dealloyed samples due to the formation of abundant active sites and the presence of defects within the CuNiCe-O composite.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 3","pages":""},"PeriodicalIF":3.2000,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11821255/pdf/","citationCount":"0","resultStr":"{\"title\":\"Boosting Electrooxidation of Ethanol by Nickel Addition to Metallic Glass Ribbon Precursors.\",\"authors\":\"Jingjing Song, Bo Zhang, Yu Chen, Qingzhuo Hu, Fabao Zhang, Langxiang Zhong\",\"doi\":\"10.3390/ma18030701\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A CuNiCe-O nanocomposite was fabricated on the Cu<sub>40</sub>Ni<sub>20</sub>Al<sub>10</sub>Ce<sub>26</sub>Pt<sub>3</sub>Ru<sub>1</sub> metallic glass (MG) ribbon surface by dealloying. The influences of Ni and dealloying time on the morphology and EOR performance were analyzed. The results suggest that the catalytic activity and stability of the dealloyed MG ribbon could be significantly enhanced owing to the alloying of Ni to the Cu<sub>60</sub>Al<sub>10</sub>Ce<sub>26</sub>Pt<sub>3</sub>Ru<sub>1</sub> MG ribbon precursor. The activated D-Cu<sub>40</sub>Ni<sub>20</sub>Al<sub>10</sub>Ce<sub>26</sub>Pt<sub>3</sub>Ru<sub>1</sub> ribbon obtained at an etching time of 3 h had a better electrochemical ethanol oxidation reaction (EOR) performance than other dealloyed samples due to the formation of abundant active sites and the presence of defects within the CuNiCe-O composite.</p>\",\"PeriodicalId\":18281,\"journal\":{\"name\":\"Materials\",\"volume\":\"18 3\",\"pages\":\"\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-02-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11821255/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.3390/ma18030701\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.3390/ma18030701","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Boosting Electrooxidation of Ethanol by Nickel Addition to Metallic Glass Ribbon Precursors.
A CuNiCe-O nanocomposite was fabricated on the Cu40Ni20Al10Ce26Pt3Ru1 metallic glass (MG) ribbon surface by dealloying. The influences of Ni and dealloying time on the morphology and EOR performance were analyzed. The results suggest that the catalytic activity and stability of the dealloyed MG ribbon could be significantly enhanced owing to the alloying of Ni to the Cu60Al10Ce26Pt3Ru1 MG ribbon precursor. The activated D-Cu40Ni20Al10Ce26Pt3Ru1 ribbon obtained at an etching time of 3 h had a better electrochemical ethanol oxidation reaction (EOR) performance than other dealloyed samples due to the formation of abundant active sites and the presence of defects within the CuNiCe-O composite.
期刊介绍：
Materials (ISSN 1996-1944) is an open access journal of related scientific research and technology development. It publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Materials provides a forum for publishing papers which advance the in-depth understanding of the relationship between the structure, the properties or the functions of all kinds of materials. Chemical syntheses, chemical structures and mechanical, chemical, electronic, magnetic and optical properties and various applications will be considered.
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