{"title":"氮磷双层配体负载的碱稳定双烷(4)的合成、表征和反应活性","authors":"Pengfei Chen, Yafei Li, Qianyi Zhao, Congqing Zhu, Qin Zhu","doi":"10.1002/cjoc.202401017","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>We synthesized a dialane(4) compound (<b>2</b>) stabilized by double-layer N-P ligands. Upon reduction with KC<sub>8</sub>, compound <b>2</b> demonstrates solvent-dependent reactivity: in THF, it undergoes C—O bond cleavage to yield product [MeN(CH<sub>2</sub>CH<sub>2</sub>NPiPr<sub>2</sub>)<sub>2</sub>Al(CH<sub>2</sub>)<sub>4</sub>O]<sub>2</sub>K<sub>2</sub>; whereas in a THF/toluene mixture, it results in the activation of the methyl C—H bond in toluene, forming product [MeN(CH<sub>2</sub>CH<sub>2</sub>NPiPr<sub>2</sub>)<sub>2</sub>AlH]<sub>2</sub>K<sub>2</sub>. We propose that these reactions involve an “Al(I)” intermediate, which facilitates oxidative addition with either the C—O bond of THF or the C—H bond of toluene.</p>\n <p>\n </p>\n </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"43 6","pages":"627-632"},"PeriodicalIF":5.7000,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Characterization and Reactivity of a Base-Stabilized Dialane(4) Supported by Double Layer Nitrogen–Phosphorus Ligands\",\"authors\":\"Pengfei Chen, Yafei Li, Qianyi Zhao, Congqing Zhu, Qin Zhu\",\"doi\":\"10.1002/cjoc.202401017\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>We synthesized a dialane(4) compound (<b>2</b>) stabilized by double-layer N-P ligands. Upon reduction with KC<sub>8</sub>, compound <b>2</b> demonstrates solvent-dependent reactivity: in THF, it undergoes C—O bond cleavage to yield product [MeN(CH<sub>2</sub>CH<sub>2</sub>NPiPr<sub>2</sub>)<sub>2</sub>Al(CH<sub>2</sub>)<sub>4</sub>O]<sub>2</sub>K<sub>2</sub>; whereas in a THF/toluene mixture, it results in the activation of the methyl C—H bond in toluene, forming product [MeN(CH<sub>2</sub>CH<sub>2</sub>NPiPr<sub>2</sub>)<sub>2</sub>AlH]<sub>2</sub>K<sub>2</sub>. We propose that these reactions involve an “Al(I)” intermediate, which facilitates oxidative addition with either the C—O bond of THF or the C—H bond of toluene.</p>\\n <p>\\n </p>\\n </div>\",\"PeriodicalId\":151,\"journal\":{\"name\":\"Chinese Journal of Chemistry\",\"volume\":\"43 6\",\"pages\":\"627-632\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-12-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cjoc.202401017\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cjoc.202401017","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis, Characterization and Reactivity of a Base-Stabilized Dialane(4) Supported by Double Layer Nitrogen–Phosphorus Ligands
We synthesized a dialane(4) compound (2) stabilized by double-layer N-P ligands. Upon reduction with KC8, compound 2 demonstrates solvent-dependent reactivity: in THF, it undergoes C—O bond cleavage to yield product [MeN(CH2CH2NPiPr2)2Al(CH2)4O]2K2; whereas in a THF/toluene mixture, it results in the activation of the methyl C—H bond in toluene, forming product [MeN(CH2CH2NPiPr2)2AlH]2K2. We propose that these reactions involve an “Al(I)” intermediate, which facilitates oxidative addition with either the C—O bond of THF or the C—H bond of toluene.
期刊介绍：
The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
