Meng Zhang, Xiaoqun Yang, Xiaolin Peng, Xiangyang Li, Zhichao Jin
{"title":"Asymmetric construction of axial and planar chirality with N-heterocyclic carbene (NHC) organocatalysis","authors":"Meng Zhang, Xiaoqun Yang, Xiaolin Peng, Xiangyang Li, Zhichao Jin","doi":"10.1007/s11426-024-2363-4","DOIUrl":null,"url":null,"abstract":"<div><p><i>N</i>-heterocyclic carbene (NHC) organocatalytic reactions that have been developed for asymmetric construction of axial and planar chirality are systematically summarized and discussed in this review. The challenges and limitations inherent to this highly reactive research field are highlighted towards the end of the review. Additionally, based on our understanding of the current advancements in NHC organocatalysis, we propose potential future directions for further exploration.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":772,"journal":{"name":"Science China Chemistry","volume":"68 3","pages":"815 - 825"},"PeriodicalIF":10.4000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Chemistry","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1007/s11426-024-2363-4","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Asymmetric construction of axial and planar chirality with N-heterocyclic carbene (NHC) organocatalysis
N-heterocyclic carbene (NHC) organocatalytic reactions that have been developed for asymmetric construction of axial and planar chirality are systematically summarized and discussed in this review. The challenges and limitations inherent to this highly reactive research field are highlighted towards the end of the review. Additionally, based on our understanding of the current advancements in NHC organocatalysis, we propose potential future directions for further exploration.
期刊介绍：
Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field.
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