杂化超级电容器用六氰高铁酸锌修饰的柔性铜基电极

IF 0.48 Q4 Physics and Astronomy Bulletin of the Russian Academy of Sciences: Physics Pub Date : 2025-02-27 DOI:10.1134/S1062873824709814
M. Kaneva, A. Levshakova, A. Lobinsky, M. Tenevich, R. Ninayan, A. Shmalko, A. Zakharov, A. Manshina, E. Khairullina
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引用次数: 0

摘要

研究了激光辅助原位合成与连续离子层吸附反应(SILAR)相结合在轻质柔性衬底上制备超级电容器的方法。重点是用六氰高铁酸锌(ZnHCF)修饰激光制造的铜电极,这是一种普鲁士蓝类似物,以其优异的电化学性能而闻名。通过循环伏安法和充放电试验对改性电极的电化学性能进行了表征,证明了改性ZnHCF在改善电荷转移动力学方面的有效性。合成的ZnHCF/Cu复合电极在电流密度为1 mA/cm2时具有182.3 mF/cm2的高比电容和良好的循环稳定性。
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Flexible Copper-Based Electrode Modified with Zinc Hexacyanoferrate as Cathode for Hybrid Supercapacitors

The integration of laser-assisted in-situ synthesis and successive ionic layer adsorption and reaction (SILAR) for the fabrication of supercapacitors on lightweight, flexible substrates is investigated. The focus was placed on the modification of laser-fabricated copper electrodes with zinc hexacyanoferrate (ZnHCF), a Prussian Blue analog known for its exceptional electrochemical properties. The electrochemical performance of the modified electrodes is characterized by cyclic voltammetry and charge-discharge tests, demonstrating the effectiveness of the ZnHCF modification in improving the charge transfer kinetics. The synthesized ZnHCF/Cu composite electrodes exhibit high specific capacitance of 182.3 mF/cm2 at a current density of 1 mA/cm2 and excellent cycling stability.

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来源期刊
Bulletin of the Russian Academy of Sciences: Physics
Bulletin of the Russian Academy of Sciences: Physics Physics and Astronomy-Physics and Astronomy (all)
CiteScore
0.90
自引率
0.00%
发文量
251
期刊介绍: Bulletin of the Russian Academy of Sciences: Physics is an international peer reviewed journal published with the participation of the Russian Academy of Sciences. It presents full-text articles (regular,  letters  to  the editor, reviews) with the most recent results in miscellaneous fields of physics and astronomy: nuclear physics, cosmic rays, condensed matter physics, plasma physics, optics and photonics, nanotechnologies, solar and astrophysics, physical applications in material sciences, life sciences, etc. Bulletin of the Russian Academy of Sciences: Physics  focuses on the most relevant multidisciplinary topics in natural sciences, both fundamental and applied. Manuscripts can be submitted in Russian and English languages and are subject to peer review. Accepted articles are usually combined in thematic issues on certain topics according to the journal editorial policy. Authors featured in the journal represent renowned scientific laboratories and institutes from different countries, including large international collaborations. There are globally recognized researchers among the authors: Nobel laureates and recipients of other awards, and members of national academies of sciences and international scientific societies.
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