不含过渡金属的1,10-邻菲罗啉促进双芳基二胺的均偶联反应

IF 2.2 3区 化学 Q2 CHEMISTRY, ORGANIC Tetrahedron Pub Date : 2025-05-01 Epub Date: 2025-02-25 DOI:10.1016/j.tet.2025.134562
Shengxing Xie, Jinxia Yang, Rong Ma, Minghui Liu, Xinyuan Zhang, Neng-Fei Wang, Chengyu Wang, Lingkai Kong
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引用次数: 0

摘要

建立了一种高效的不含过渡金属的1,10-菲罗啉促进的均偶联反应,以2-碘苯并胺为原料合成联芳基二胺。在标准反应条件下,以容易获得的原料,以良好的收率顺利地合成了各种需要的产物。该方法具有广泛的底物范围和良好的官能团耐受性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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A transition-metal-free 1,10-phenanthroline-promoted homocoupling reaction for the construction of biaryl diamides
An efficient transition-metal-free 1,10-phenanthroline-promoted homocoupling reaction has been developed to construct biaryl diamides from 2-iodobenzamides. Various desired products were smoothly synthesized with readily available starting materials in good to excellent yields under the standard reaction conditions. And this method showed a wide substrate scope and good functional group tolerance.
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来源期刊
Tetrahedron
Tetrahedron 化学-有机化学
CiteScore
3.90
自引率
4.80%
发文量
439
审稿时长
34 days
期刊介绍: Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.
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