Negative-Ion Formation upon Soft X-ray Photoexcitation of 2-Propanol.

This study investigates the formation of negative ion fragments from gas-phase 2-propanol molecules after interaction with soft X-rays near the O K-edge. The experiment was performed by detecting negative and positive ions in coincidence with time-of-flight spectrometry. The analysis of two- and three-ion coincidence data revealed that nine different anions were produced: H^-, C^-, CH^-, CH₂^-, O^-, OH^-, C₂^-, C₂H^-, and C₃^-. For all anions, the most common three-ion events were those involving two protons. The results highlight the sensitivity of negative-ion/positive-ion coincidence spectroscopy and provide new insight into the fragmentation processes of organic molecules under soft X-ray excitation.