制备轻质、高强聚氯乙烯-木材复合材料的蒸发诱导压缩成型策略

IF 4.4 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science Pub Date : 2025-02-19 DOI:10.1007/s10853-025-10709-9
Zheng Li, Yanxin Yin, Zhibing Zhang, Jianxian Zeng, Pengfei Liu, Gaopan Dong, Zhengqiu Yuan
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引用次数: 0

摘要

木塑复合材料(WPC)加工为回收聚氯乙烯(PVC)提供了一种可持续和有效的方法,聚氯乙烯是最常用的热塑性塑料之一。然而,传统的制造技术往往需要高温条件,限制了它们的实用性和环境效率。本研究介绍了一种利用蒸发诱导压缩成型策略在常温下组装木塑材料的新方法。以废木粉为填料,聚氯乙烯为基体。以四氢呋喃(THF)为溶剂,加入偶联剂γ-甲基丙烯氧基丙基三甲氧基硅烷(KH570)和抗氧化剂1076,提高了界面相容性和材料性能。利用力学性能测试、扫描电子显微镜、傅里叶变换红外光谱和x射线衍射对WPC进行了全面表征。此外,还分析了复合材料的密度、吸水率和孔隙率。并对木塑材料的隔音和隔热性能进行了评价。结果表明,松木粉:THF:PVC的比例为4:6:4(质量:体积:质量)时,获得了最佳的材料组成。该组合物的抗弯强度为14.8 MPa,抗拉强度为7.65 MPa。此外,木塑材料表现出优异的隔音和隔热性能,突出了其实际应用的潜力。这项研究为木塑复合材料的制造提供了一种开创性的环保方法。图形抽象
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Evaporation-Induced Compression Molding Strategy for the fabrication of lightweight, high-strength polyvinyl chloride–wood composites

Wood-plastic composites (WPC) processing offers a sustainable and efficient method for recycling polyvinyl chloride (PVC), one of the most commonly used thermoplastics. However, traditional fabrication techniques often require high-temperature conditions, limiting their practicality and environmental efficiency. This study introduces a novel method for assembling WPC at ambient temperature using the Evaporation-Induced Compression Molding Strategy. Waste wood flour was employed as the filler material, while PVC served as the matrix. Tetrahydrofuran (THF) acted as the solvent, supplemented by the coupling agent γ-methacryloxypropyltrimethoxysilane (KH570) and antioxidant 1076 to enhance interfacial compatibility and material performance. Comprehensive characterization of the WPC was performed using mechanical performance testing, scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. Additionally, the density, water absorption, and porosity of the composites were analyzed. The acoustic and thermal insulation properties of the WPC were also evaluated. The results revealed that the optimal material composition was achieved with a pinewood flour:THF:PVC ratio of 4:6:4 (mass:volume:mass). This composition delivered a bending strength of 14.8 MPa and a tensile strength of 7.65 MPa. Moreover, the WPC demonstrated excellent acoustic and thermal insulation properties, highlighting its potential for practical applications. This study provides a groundbreaking and environmentally friendly approach to the fabrication of wood-plastic composites.

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来源期刊
Journal of Materials Science
Journal of Materials Science 工程技术-材料科学:综合
CiteScore
7.90
自引率
4.40%
发文量
1297
审稿时长
2.4 months
期刊介绍: The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.
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