改进的Zn1-xCuxO纳米结构薄膜光电子应用的电学、紫外探测和发射性能

IF 2.8 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Physica B-condensed Matter Pub Date : 2025-05-15 Epub Date: 2025-03-03 DOI:10.1016/j.physb.2025.417110
Ziaul Raza Khan , M. Bouzidi , Mansour Mohamed , Siddhartha
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引用次数: 0

摘要

氧化锌是金属氧化物中具有生物相容性和化学稳定性的材料。采用自旋镀膜技术,分别在x = 0.0、1.0、2.0和3.0 wt% Cu掺杂条件下生长了Zn1-xCuxO薄膜。薄膜的物理性质,如结构,形态和光学性质,通过各种表征技术进行检查。样品的x射线衍射图在2θ角~ 34.5°处有清晰而强烈的峰,为六方纤锌矿相。用拉曼光谱法确定了薄膜的振动模式,其中心为500和1050 cm−1,对应于ZnO的纯六方纤锌矿相。纯ZnO薄膜具有较高的透光率~ 90%,在ZnO基体中引入Cu后,透光率降低。室温光致发光光谱表现为近带边发射峰和宽可见发射。在ZnO晶格中掺杂Cu后,薄膜的电学性能和紫外光响应得到了显著改善。因此,Cu掺杂ZnO薄膜在光电子学应用方面具有很高的潜力。
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Improved electrical, UV detection and emission properties of Zn1-xCuxO nano structured thin films for optoelectronics applications
ZnO oxide is biocompatible and chemically stable material among metal oxides. Zn1-xCuxO thin films have been grown with x = 0.0, 1.0, 2.0 and 3.0 wt% Cu doping through spin coater technique. Films physical properties such as structural, morphology and optical properties are examined via various characterization techniques. X-ray diffractograms of specimen exhibits clear and intense peak at 2θ angle ∼34.5°, refers the hexagonal wurtzite phase. Films vibrational modes are identified using Raman spectroscopy that is centered at 500 and 1050 cm−1 corresponds to pure hexagonal wurtzite phase of ZnO. Pure ZnO film showed high transmittance∼90 %, after introduction of Cu in ZnO matrix, it become reduced. The room temperature photoluminescence spectra is shown near band edge emission peak along with broad visible emission. Films electrical properties and UV Photoresponse shows the significant improvement upon Cu doping in ZnO lattice. Therefore, Cu incorporated ZnO thin films demonstrates high potentiality towards the optoelectronics applications.
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来源期刊
Physica B-condensed Matter
Physica B-condensed Matter 物理-物理:凝聚态物理
CiteScore
4.90
自引率
7.10%
发文量
703
审稿时长
44 days
期刊介绍: Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work. Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas: -Magnetism -Materials physics -Nanostructures and nanomaterials -Optics and optical materials -Quantum materials -Semiconductors -Strongly correlated systems -Superconductivity -Surfaces and interfaces
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