BiVO4-ZnO纳米复合材料的制备与表征及其在废水处理和提高电极性能方面的应用

IF 2.6 4区 化学 Q3 CHEMISTRY, PHYSICAL Ionics Pub Date : 2025-01-22 DOI:10.1007/s11581-025-06079-6
Kannan Nagarajan, Sundara Venkatesh Perumalsamy, Vijayalakshmi Seenivasan, Jeganathan Kulandaivel, Thangadurai Paramasivam, Jayanthi Santhana Krishnan
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引用次数: 0

摘要

本文主要研究了BiVO4-ZnO纳米复合材料(NC)的合成及其光催化染料降解和介电应用。与单个组分相比,合成的NC具有更好的结构、光催化和介电性能。x射线衍射证实了单斜斜BiVO4和六方纤锌矿ZnO晶体结构的存在。FESEM图像显示分散良好的球形ZnO和片状BiVO4纳米结构。NC在15分钟内实现了令人印象深刻的98%的亚甲基蓝(MB)染料分子降解,这比母材料快了近四倍。此外,光稳定性测试在五个循环中显示出优异的性能,自由基捕获实验强调了空穴和羟基自由基在光降解过程中的作用。此外,介电测量表明,高介电常数为36.18,低损耗系数为0.80。这些发现表明BiVO4-ZnO纳米复合材料是一种很有前景的环境修复和储能材料。图形抽象
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Preparation and characterization of BiVO4-ZnO nanocomposite as heterogeneous photocatalysts for wastewater treatment and enhanced electrode performance

This study focuses on the synthesis and investigation of a BiVO4-ZnO nanocomposite (NC) for photocatalytic dye degradation and dielectric applications. The synthesized NC exhibits improved structural, photocatalytic, and dielectric properties compared to its individual components. X-ray diffraction confirms the presence of monoclinic BiVO4 and hexagonal wurtzite ZnO crystal structures. FESEM images show well-dispersed spherical ZnO and flaky BiVO4 nanostructures. The NC achieves an impressive 98% degradation of methylene blue (MB) dye molecules in just 15 min, which is nearly four times faster than the parent materials. Additionally, photo-stability tests demonstrate excellent performance over five cycles, and radical trapping experiments highlight the roles of holes and hydroxyl radicals in the photodegradation process. Furthermore, dielectric measurements reveal a high dielectric constant of 36.18 and a low loss factor of 0.80. These findings suggest that the BiVO4-ZnO nanocomposite is a promising material for environmental remediation and energy storage applications.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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