Zilong Chen, Bingliang Cheng, Abudukadi Tudi, Xiaojing Li, Zhihua Yang, Fangfang Zhang, Shilie Pan
{"title":"金属阳离子诱导的三种不同尺寸框架硼酸盐","authors":"Zilong Chen, Bingliang Cheng, Abudukadi Tudi, Xiaojing Li, Zhihua Yang, Fangfang Zhang, Shilie Pan","doi":"10.1021/acs.inorgchem.5c00066","DOIUrl":null,"url":null,"abstract":"Three new metal borates containing d<sup>10</sup> cations, namely, Li<sub>4</sub>PbZn<sub>3</sub>B<sub>12</sub>O<sub>24</sub>, Na<sub>2</sub>Cd<sub>2</sub>B<sub>8</sub>O<sub>15,</sub> and K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub>, were synthesized using the flux method. K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub> is the first Zn-containing borate carbonate and has an unprecedented fundamental building block, [B<sub>10</sub>O<sub>22</sub>]. Furthermore, experimental and first-principles theoretical studies were performed.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"2 1","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations\",\"authors\":\"Zilong Chen, Bingliang Cheng, Abudukadi Tudi, Xiaojing Li, Zhihua Yang, Fangfang Zhang, Shilie Pan\",\"doi\":\"10.1021/acs.inorgchem.5c00066\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Three new metal borates containing d<sup>10</sup> cations, namely, Li<sub>4</sub>PbZn<sub>3</sub>B<sub>12</sub>O<sub>24</sub>, Na<sub>2</sub>Cd<sub>2</sub>B<sub>8</sub>O<sub>15,</sub> and K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub>, were synthesized using the flux method. K<sub>2</sub>Sr<sub>4</sub>ZnB<sub>10</sub>O<sub>19</sub>(CO<sub>3</sub>)<sub>2</sub> is the first Zn-containing borate carbonate and has an unprecedented fundamental building block, [B<sub>10</sub>O<sub>22</sub>]. Furthermore, experimental and first-principles theoretical studies were performed.\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\"2 1\",\"pages\":\"\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.inorgchem.5c00066\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.5c00066","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations
Three new metal borates containing d10 cations, namely, Li4PbZn3B12O24, Na2Cd2B8O15, and K2Sr4ZnB10O19(CO3)2, were synthesized using the flux method. K2Sr4ZnB10O19(CO3)2 is the first Zn-containing borate carbonate and has an unprecedented fundamental building block, [B10O22]. Furthermore, experimental and first-principles theoretical studies were performed.
期刊介绍：
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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