A. S. Zavgorodnii, M. A. Kryukova, A. Y. Timoshkin
{"title":"路易斯酸Ga[N(C6F5)2]3与吡啶和乙醚的给受体配合物","authors":"A. S. Zavgorodnii, M. A. Kryukova, A. Y. Timoshkin","doi":"10.1134/S0022476625020040","DOIUrl":null,"url":null,"abstract":"<p>Donor-acceptor complexes of the Ga[N(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>]<sub>3</sub> Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 2","pages":"251 - 260"},"PeriodicalIF":1.5000,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Donor-Acceptor Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Pyridine and Diethyl Ether\",\"authors\":\"A. S. Zavgorodnii, M. A. Kryukova, A. Y. Timoshkin\",\"doi\":\"10.1134/S0022476625020040\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Donor-acceptor complexes of the Ga[N(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>]<sub>3</sub> Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"66 2\",\"pages\":\"251 - 260\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-03-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476625020040\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476625020040","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Donor-Acceptor Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Pyridine and Diethyl Ether
Donor-acceptor complexes of the Ga[N(C6F5)2]3 Lewis acid with pyridine and diethyl ether are prepared for the first time and characterized by single-crystal XRD. The gallium atom in the complexes has a trigonal-pyramidal environment with bond angles significantly differing from the tetrahedral ones, indicating a hindered character of the transformation of the Lewis acid from the free state to the geometry of the donor-acceptor complex.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
