基于生物质棉和Ni @纳米多孔碳的简易合成及绿色高性能电磁波吸收复合材料

IF 2.4 3区 化学 Q4 CHEMISTRY, PHYSICAL Chemical Physics Pub Date : 2025-07-01 Epub Date: 2025-03-25 DOI:10.1016/j.chemphys.2025.112716
Zexuan Wang , Sen Lei , Chenge Liu , Ling Zhang , Xin Ma , Mingyang Gao , Qiang Li , Cheng Chen , Wu Zhao
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引用次数: 0

摘要

近年来,电磁污染日益受到人们的关注,电磁波吸收材料越来越多地用于减轻其影响。本研究提出了一种生物质棉/镍mofs衍生的Ni@纳米多孔碳@碳纤维(Ni@ NPC@ CF)复合材料,采用水热和热分解方法制备。显微观察表明,Ni@ NPC@ CF在碳纤维基体上分布均匀。复合材料表现出多种电磁波损耗机制:纳米镍颗粒的磁损耗和纳米多孔碳和碳纤维的电损耗。当填充率为20%,厚度为2.75 mm时,该材料的RLmin为- 67 dB,有效吸收带宽(EAB)为7.23 GHz (RL <;-10分贝)。该研究为利用生物质作为一种高性能、低成本、环保、可再生的碳基吸收材料提供了一种实用的解决方案,为开发电磁波吸收复合材料提供了有价值的见解。
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Facile synthesis and green high-performance electromagnetic wave absorbing composite material based on biomass cotton and Ni @ nanoporous carbon
In recent years, electromagnetic pollution has become a growing concern, and electromagnetic wave absorption materials are increasingly used to mitigate its effects. This study presents a biomass cotton/nickel MOFs-derived Ni@ nanoporous carbon@ carbon fiber (Ni@ NPC@ CF) composite material, prepared using hydrothermal and thermal decomposition methods. Microscopic observations reveal a uniform distribution of Ni@ NPC@ CF on the carbon fiber matrix. The composite exhibits multiple electromagnetic wave loss mechanisms: magnetic loss from nano‑nickel particles and electrical loss from nanoporous carbon and carbon fibers. With only a 20 % filling ratio and a thickness of 2.75 mm, the material achieves an RLmin of −67 dB and an effective absorption bandwidth (EAB) of 7.23 GHz (RL < -10 dB). This study offers a practical solution for utilizing biomass as a high-performance, cost-effective, eco-friendly, and renewable carbon-based absorbent material, providing valuable insights for developing electromagnetic wave absorbing composites.
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来源期刊
Chemical Physics
Chemical Physics 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
4.30%
发文量
278
审稿时长
39 days
期刊介绍: Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.
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