研制具有催化层的直接乙醇金属支撑燃料电池

IF 5.7 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Science and Engineering: B Pub Date : 2025-08-01 Epub Date: 2025-03-29 DOI:10.1016/j.mseb.2025.118259
S.G.M. Carvalho , F.N. Tabuti , E.I. Santiago , R. Abe , R.M. Guimarães , Y. Miura , Y. Fukuyama , F.C. Fonseca
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引用次数: 0

摘要

燃料电池是一种高效的能源,在能源转型中发挥着重要作用。直接乙醇燃料电池可以促进固体氧化物燃料电池的应用,因为乙醇是一种高效、可持续和容易获得的燃料。金属支撑的固体氧化物燃料电池为车辆等复杂应用提供了必要的机械性能。因此,可再生燃料和强大的燃料电池的结合可能是交通运输广泛脱碳的完美组合,由经济可行和高能量高效的液体燃料促进。然而,要延长这种以乙醇为燃料的装置的耐用性,仍存在一些挑战。我们报道了通过使用与金属支撑固体氧化物燃料电池技术兼容的工艺参数,添加具有可控微观结构的多孔活性催化层,显著改善了金属支撑燃料电池在相对低温(700°C)下使用乙醇工作的稳定性。
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Advancing direct ethanol metal supported fuel cells with catalytic layer
Fuel cells are efficient power sources to play a role in the urgent energy transition. Direct ethanol fuel cells may boost the application of solid oxide fuel cell because ethanol is an efficient, sustainable, and readily available fuel. Metal supported solid oxide fuel cells provide the necessary mechanical properties to allow complex applications such as vehicles. Thus, the combination of a renewable fuel and a robust fuel cell may be a perfect combination for widespread decarbonization of transportation, facilitated by an economic viable and energetic efficient liquid fuel. However, several challenges remain to prolong the durability of such devices running on ethanol. We report on the significant improvement of the metal supported fuel cell stability operating at relatively low temperature (700 °C) with ethanol by adding a porous active catalytic layer with controlled microstructure using processing parameters compatible with the metal-supported solid oxide fuel cell technology.
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来源期刊
Materials Science and Engineering: B
Materials Science and Engineering: B 工程技术-材料科学:综合
CiteScore
5.60
自引率
2.80%
发文量
481
审稿时长
3.5 months
期刊介绍: The journal provides an international medium for the publication of theoretical and experimental studies and reviews related to the electronic, electrochemical, ionic, magnetic, optical, and biosensing properties of solid state materials in bulk, thin film and particulate forms. Papers dealing with synthesis, processing, characterization, structure, physical properties and computational aspects of nano-crystalline, crystalline, amorphous and glassy forms of ceramics, semiconductors, layered insertion compounds, low-dimensional compounds and systems, fast-ion conductors, polymers and dielectrics are viewed as suitable for publication. Articles focused on nano-structured aspects of these advanced solid-state materials will also be considered suitable.
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