锰催化巯基与P(O)H化合物的好氧交叉脱氢偶联

IF 1.4 4区化学 Q3 CHEMISTRY, ORGANIC Tetrahedron Letters Pub Date : 2025-05-15 Epub Date: 2025-03-29 DOI:10.1016/j.tetlet.2025.155566

Bing Han , Yuge Ji , Jing Qin , Lei Liu , Gang Wang

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引用次数: 0

摘要

以空气为氧化剂，建立了锰催化硫醇和P(O)H化合物的高效交叉脱氢偶联反应。该系统简单环保，具有良好的基材范围和功能基团耐受性。芳基和烷基硫醇与P(O)H化合物可以很好地合成相应的硫代磷酸盐，收率很高。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Manganese-catalyzed aerobic cross-dehydrogenative coupling of thiols with P(O)H compounds

An efficient manganese-catalyzed cross-dehydrogenative coupling of thiols and P(O)H compounds with air as the oxidant has been established. This simple and green system has a good substrate scope and functional group tolerance. Aryl and alkyl thiols worked well with P(O)H compounds to produce the corresponding thiophosphates in good to excellent yields.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.