{"title":"用箱车积分器测量电子自旋共振实验中的弛豫时间。","authors":"R Isaacson","doi":"10.1088/0022-3735/1/11/425","DOIUrl":null,"url":null,"abstract":"Field modulation is used with pulsed electron spin resonance apparatus to measure the relaxation time T1 of weak but easily saturable paramagnetic resonances. Both a boxcar integrator and lock-in detector are used to recover the field modulation signal from the noise. The method works best for T1 between about 1 μs and 1/10 of the field modulation period (e.g. approximately 1 ms for 100 cycles) but it may be used to measure longer relaxation times also.","PeriodicalId":16983,"journal":{"name":"Journal of Scientific Instruments","volume":"1 11","pages":"1137-9"},"PeriodicalIF":0.0000,"publicationDate":"1968-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1088/0022-3735/1/11/425","citationCount":"8","resultStr":"{\"title\":\"Use of field modulation with boxcar integrator to measure relaxation time in electron spin resonance experiments.\",\"authors\":\"R Isaacson\",\"doi\":\"10.1088/0022-3735/1/11/425\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Field modulation is used with pulsed electron spin resonance apparatus to measure the relaxation time T1 of weak but easily saturable paramagnetic resonances. Both a boxcar integrator and lock-in detector are used to recover the field modulation signal from the noise. The method works best for T1 between about 1 μs and 1/10 of the field modulation period (e.g. approximately 1 ms for 100 cycles) but it may be used to measure longer relaxation times also.\",\"PeriodicalId\":16983,\"journal\":{\"name\":\"Journal of Scientific Instruments\",\"volume\":\"1 11\",\"pages\":\"1137-9\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1968-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1088/0022-3735/1/11/425\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Scientific Instruments\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1088/0022-3735/1/11/425\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Scientific Instruments","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1088/0022-3735/1/11/425","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Use of field modulation with boxcar integrator to measure relaxation time in electron spin resonance experiments.
Field modulation is used with pulsed electron spin resonance apparatus to measure the relaxation time T1 of weak but easily saturable paramagnetic resonances. Both a boxcar integrator and lock-in detector are used to recover the field modulation signal from the noise. The method works best for T1 between about 1 μs and 1/10 of the field modulation period (e.g. approximately 1 ms for 100 cycles) but it may be used to measure longer relaxation times also.