带挡板的垂向Bridgman生长中的盘状驱动流动和界面形状

IF 4.5 2区 材料科学 Q1 CRYSTALLOGRAPHY Progress in Crystal Growth and Characterization of Materials Pub Date : 2021-02-01 DOI:10.1016/j.pcrysgrow.2020.100512
A.G. Ostrogorsky
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引用次数: 6

摘要

在垂直Bridgman (VB)体系中,由于与坩埚的连续接触,S-L界面的形状对单晶的成品率和完美性有很大的影响。熔体流动和S-L界面形状难以改变和控制。挡板是引导或阻碍流动的装置。在VB熔体中,挡板呈圆盘状,水平放置在固液界面上方。挡板的作用是:i)最小化热驱动对流ii)控制/减少向S-L界面的轴向传热iii)产生盘驱动流动。此外,挡板起到隔板的作用,将熔体分成:生长熔体在挡板下方,进料熔体在挡板上方。强制对流是完全消除热驱动非定常流这种不太可行和可靠的选择的一个实际替代方案。在CZ工艺中,晶体旋转驱动的流量是VB工艺所缺乏的关键控制参数。挡板旋转带来了类似于cz的流动进入VB过程。圆盘驱动的流动是各种科学和工程应用的最佳选择,因为圆盘表面的层流边界层稳定且厚度均匀。在VB熔体中,挡板的导热系数及其旋转速率决定了界面形状,从而决定了单晶的良率和完美性。在旋转挡板下,自然对流对生产尺寸熔体的影响可以忽略不计。
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Disk-driven flows and interface shape in vertical Bridgman growth with a baffle

In vertical Bridgman (VB) systems, the shape of the S-L interface greatly influences the yield and perfection of single crystal, because of the continuous contact with the crucible. The melt flows and the shape of the S-L interface are difficult to modify and control.

Baffles are flow-directing or obstructing devices. In VB melts, the baffles are disk shaped, and positioned horizontally above the solid-liquid (S-L) interface. The role of the baffle is to: i) minimize the thermally-driven convection ii) control/reduce the axial heat transfer to the S-L interface and iii) generate the disk-driven flows. Furthermore, the baffle acts as a partition, splitting the melt into: the growth melt below the baffle and the feeding melt above the baffle.

Forced convection is a practical alternative to the less feasible and reliable option of completely eliminating thermally-driven unsteady flows. In the Czochralski (CZ) process, the flow driven by crystal rotation is a key control parameter which the VB process lacks. Baffle rotation brings the CZ-like flow into the VB process. The disk-driven flows are optimal for various scientific and engineering applications because the laminar boundary layers at the disk surface are steady and have uniform thickness.

In VB melts, the thermal conductivity of the baffle and its rotation rate dominate the interface shape and thus the yield and perfection of single crystals. Under the rotating baffle, the effects of natural convection can be made negligible in production size melts.

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来源期刊
Progress in Crystal Growth and Characterization of Materials
Progress in Crystal Growth and Characterization of Materials 工程技术-材料科学:表征与测试
CiteScore
8.80
自引率
2.00%
发文量
10
审稿时长
1 day
期刊介绍: Materials especially crystalline materials provide the foundation of our modern technologically driven world. The domination of materials is achieved through detailed scientific research. Advances in the techniques of growing and assessing ever more perfect crystals of a wide range of materials lie at the roots of much of today''s advanced technology. The evolution and development of crystalline materials involves research by dedicated scientists in academia as well as industry involving a broad field of disciplines including biology, chemistry, physics, material sciences and engineering. Crucially important applications in information technology, photonics, energy storage and harvesting, environmental protection, medicine and food production require a deep understanding of and control of crystal growth. This can involve suitable growth methods and material characterization from the bulk down to the nano-scale.
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