檀香气味剂的手性识别。

Enantiomer Pub Date : 2000-01-01
J A Bajgrowicz, G Frater
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引用次数: 0

摘要

为了寻找更有效的檀香油味化合物,制备了具有刚性环丙烷环的新型樟脑醛衍生物。对于其中一些,具有最低的气味阈值,这种类型的气味和非常受欢迎的气味,接近稀缺的天然檀香油,获得了纯立体异构体,并评估了它们的嗅觉特性。因此,获得的结构-气味关系数据,以及巩固和完成的先前关于不同结构檀香气味化合物的知识,允许提出檀香嗅觉基团的新模型。
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Chiral recognition of sandalwood odorants.

Looking for more efficient sandalwood oil smelling compounds, new campholenic aldehyde derivatives with rigidifying cyclopropane rings were prepared. For some of them, having the lowest odor threshold ever measured for this type of odorants and a very appreciated scent, close to that of the scarce natural sandalwood oils, pure stereoisomers were obtained and their olfactory properties were evaluated. Thus acquired structure-odor relationship data, together with consolidated and completed previous knowledge on structurally different sandalwood-smelling compounds, allowed to propose new models of the sandalwood olfactophore.

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