固体氧化物燃料电池金属互连研究进展。

Wei-Zhong Zhu, Mi Yan
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引用次数: 28

摘要

综述了近二十年来固体氧化物燃料电池(SOFCs)互连材料发展的各个阶段和进展。强调了材料作为互连体的应用标准。基于镧铬铁陶瓷的互连显示出许多固有的缺点,因此仅适用于工作在1000摄氏度左右的sofc。阳极支撑的扁平sofc研究的进展有助于用金属互连代替陶瓷互连,因为它们的工作温度大大降低。此外,与陶瓷相比,由金属或合金制成的互连具有许多优点。对各种有前景的金属互连体的氧化响应和热膨胀行为进行了研究和评价。在金属互连的预期使用寿命内,最小化接触电阻以实现所需的可靠堆叠性能仍然是一个极具挑战性的问题。廉价的涂层材料和技术可能在促进SOFC堆叠的商业化方面发挥关键作用,SOFC堆叠的互连是由一些现有的市售合金构成的。或者,需要开发新的金属材料,能够形成稳定的氧化鳞片,生长速度缓慢,具有足够的导电性。
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Perspectives on the metallic interconnects for solid oxide fuel cells.

The various stages and progress in the development of interconnect materials for solid oxide fuel cells (SOFCs) over the last two decades are reviewed. The criteria for the application of materials as interconnects are highlighted. In-terconnects based on lanthanum chromite ceramics demonstrate many inherent drawbacks and therefore are only useful for SOFCs operating around 1000 degrees C. The advance in the research of anode-supported flat SOFCs facilitates the replacement of ceramic interconnects with metallic ones due to their significantly lowered working temperature. Besides, interconnects made of metals or alloys offer many advantages as compared to their ceramic counterpart. The oxidation response and thermal expansion behaviors of various prospective metallic interconnects are examined and evaluated. The minimization of contact resistance to achieve desired and reliable stack performance during their projected lifetime still remains a highly challenging issue with metallic interconnects. Inexpensive coating materials and techniques may play a key role in pro-moting the commercialization of SOFC stack whose interconnects are constructed of some current commercially available alloys. Alternatively, development of new metallic materials that are capable of forming stable oxide scales with sluggish growth rate and sufficient electrical conductivity is called for.

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