电磁屏蔽用铁氧体/聚吡咯复合材料的合成与表征

IF 1.9 4区 材料科学 Q3 Materials Science Journal of the Australian Ceramic Society Pub Date : 2023-05-03 DOI:10.1007/s41779-023-00887-7
Muhammad Zeshan, El-Sayed M. Sherif, Mohd Zahid Ansari, Hafiz Muhammad Tahir Farid
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引用次数: 2

摘要

铁氧体聚合物复合材料是磁性和聚合物性能的无缝融合,体现了强度和灵活性,为创新应用的新时代铺平了道路。以尖晶石铁氧体和聚吡咯(PPy)为原料,采用标准陶瓷法合成了BaFe2O4/聚吡咯复合纳米材料。x射线衍射(XRD)结果表明,尖晶石铁素体均匀分布于单相py -基体中。由于聚吡啶是无定形的,随着基体中尖晶石铁素体含量的增加,纳米复合材料中晶体的尺寸也随之增大。在较高的频率下,由于极化效应降低,复合材料的介电损耗降低。在PPy基体中加入纳米粒子使传导通道变窄,导致活化能和电阻率增加。通过添加铁氧体组分,增强了复合材料的磁性能。结果表明,所制备的复合材料有可能成为电磁干扰屏蔽的潜在候选材料。
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Synthesis and characterizations of ferrite/polypyrrole composites for electromagnetic shielding

Ferrite polymer composites, a seamless fusion of magnetic and polymeric properties, embody both strength and flexibility, paving the way for a new era of innovative applications. Composite nanomaterials of BaFe2O4/polypyrrole were synthesized by combining spinel ferrites and polypyrrole (PPy) by standard ceramic method. The X-ray diffraction (XRD) measurements revealed that the spinel ferrites were uniformly distributed throughout the single-phase PPy-matrix. Because PPy is amorphous, the size of the crystallites in nanocomposites grew as the amount of spinel ferrite in the matrix went up. At higher frequencies, the dielectric loss of the composites decreases due to reduced polarization effects. The addition of nanoparticles to the PPy matrix made the conduction channel narrower, leading to increased activation energy and resistivity. The magnetic properties of the composites were enhanced by adding ferrite components. The obtained results indicate that the prepared composites may be a potential candidate for EMI shielding applications.

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来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society MATERIALS SCIENCE, CERAMICS-
CiteScore
3.20
自引率
5.30%
发文量
1
审稿时长
>12 weeks
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
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