土耳其东黑海地区路边地衣样本中痕量金属含量。

Ozgur Dogan Uluozlu, Kadir Kinalioglu, Mustafa Tuzen, Mustafa Soylak
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引用次数: 0

摘要

目的:测定土耳其东黑海地区地衣种类中金属含量,为交通污染调查提供依据。方法:采用微波消解法,采用火焰原子吸收法和石墨炉原子吸收光谱法测定土耳其东黑海地区地衣样品中铜、镉、铅、锌、锰、铁、铬、镍、钴、钯的含量。采用标准标准物质(NIST SRM IAEA-336地衣)对方法的准确度进行了校正。结果:地衣样品中微量金属铜含量为7.19 ~ 22.4微克/g,镉含量为0.10 ~ 0.64微克/g,铅含量为4.03 ~ 44.6微克/g,锌含量为14.5 ~ 41.8微克/g,锰含量为25.8 ~ 208微克/g,铁含量为331 ~ 436微克/g,铬含量为1.20 ~ 3.01微克/g,镍含量为1.48 ~ 3.90微克/g,钴含量为0.20 ~ 3.55微克/g,钯含量为0.11 ~ 0.64微克/g。结果与文献值进行比较。结论:一些地衣物种如黄原菌、钙黄菌、膜黄原菌和垂枝黄原菌具有较高的微量金属积累率。
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Trace metal levels in lichen samples from roadsides in East Black Sea region, Turkey.

Objective: To determine the metal contents of lichen species from East Black Sea region of Turkey for investigation of trace metal pollution sourced traffic.

Methods: The levels of copper, cadmium, lead, zinc, manganese, iron, chromium, nickel, cobalt, palladium in lichen samples collected from East Black Sea region of Turkey were determined by flame and graphite furnace atomic absorption spectrometry after microwave digestion method. The accuracy of the method was corrected by standard reference material (NIST SRM IAEA-336 Lichen).

Results: The contents of investigated trace metals in lichen samples were 7.19-22.4 microg/g for copper, 0.10-0.64 microg/g for cadmium, 4.03-44.6 microg/g for lead, 14.5-41.8 microg/g for zinc, 25.8-208 microg/g for manganese, 331-436 microg/g for iron, 1.20-3.01 microg/g for chromium, 1.48-3.90 microg/g for nickel, 0.20-3.55 microg/g for cobalt, 0.11-0.64 microg/g for palladium. The results were compared with the literature values.

Conclusion: Some lichen species such as Xanthoparmelia conspersa, Xanthoria calcicola, Peltigera membranacea, and Physcia adscendens are accumulated trace metals at a high ratio.

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