晶体学的成功故事。

IF 1.8 4区 材料科学 Acta Crystallographica Section A Pub Date : 2012-01-01 Epub Date: 2011-12-20 DOI:10.1107/S0108767311030303
Dieter Schwarzenbach
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引用次数: 15

摘要

衍射学家通常把晶体学的诞生放在弗里德里希、尼平和劳的第一次x射线衍射实验的1912年。这一发现推动了矿物学的数学分支在全球的重要性,并使晶体结构的确定成为可能。原子分辨率下物质几何结构的知识对自然科学的所有分支都产生了革命性的影响:物理学、化学、生物学、地球科学和材料科学。一个人在一篇文章中几乎不可能追踪和适当地评价所有这些发展。这篇文章提出了有限的,主观的观点,其作者和有限的参考文献选择。文章的大部分内容涵盖了从NaCl结构到非周期结构和大分子结构的x射线结构测定的历史。到1920年,已有了理论基础。晶体学后来的成功是由于衍射设备的发展,相问题的解决理论,对称理论和计算机。许多已知的结构要求晶体化学和数据库的发展。无或有部分长程有序的无序结构的漫射散射允许确定短程有序。也提到了中子和电子的散射和衍射。
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The success story of crystallography.

Diffractionists usually place the birth of crystallography in 1912 with the first X-ray diffraction experiment of Friedrich, Knipping and Laue. This discovery propelled the mathematical branch of mineralogy to global importance and enabled crystal structure determination. Knowledge of the geometrical structure of matter at atomic resolution had revolutionary consequences for all branches of the natural sciences: physics, chemistry, biology, earth sciences and material science. It is scarcely possible for a single person in a single article to trace and appropriately value all of these developments. This article presents the limited, subjective view of its author and a limited selection of references. The bulk of the article covers the history of X-ray structure determination from the NaCl structure to aperiodic structures and macromolecular structures. The theoretical foundations were available by 1920. The subsequent success of crystallography was then due to the development of diffraction equipment, the theory of the solution of the phase problem, symmetry theory and computers. The many structures becoming known called for the development of crystal chemistry and of data banks. Diffuse scattering from disordered structures without and with partial long-range order allows determination of short-range order. Neutron and electron scattering and diffraction are also mentioned.

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来源期刊
自引率
11.10%
发文量
0
审稿时长
3 months
期刊介绍: Acta Crystallographica Section A: Foundations and Advances publishes articles reporting advances in the theory and practice of all areas of crystallography in the broadest sense. As well as traditional crystallography, this includes nanocrystals, metacrystals, amorphous materials, quasicrystals, synchrotron and XFEL studies, coherent scattering, diffraction imaging, time-resolved studies and the structure of strain and defects in materials. The journal has two parts, a rapid-publication Advances section and the traditional Foundations section. Articles for the Advances section are of particularly high value and impact. They receive expedited treatment and may be highlighted by an accompanying scientific commentary article and a press release. Further details are given in the November 2013 Editorial. The central themes of the journal are, on the one hand, experimental and theoretical studies of the properties and arrangements of atoms, ions and molecules in condensed matter, periodic, quasiperiodic or amorphous, ideal or real, and, on the other, the theoretical and experimental aspects of the various methods to determine these properties and arrangements.
期刊最新文献
A new vision for Acta Crystallographica Section A. Nets with collisions (unstable nets) and crystal chemistry. Homometry in the light of coherent beams. More about residual values. Direct phasing of nanocrystal diffraction.
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