丙烯酸接枝共聚聚酯织物表面改性及其抗菌性能。

ISRN Organic Chemistry Pub Date : 2011-04-07 eCollection Date: 2011-01-01 DOI:10.5402/2011/265415
M Abdolahifard, S Hajir Bahrami, R M A Malek
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引用次数: 33

摘要

用过氧化苯甲酰进行了丙烯酸(AA)与聚对苯二甲酸乙酯(PET)织物的接枝共聚。研究了聚合参数对接枝收率的影响。当过氧化苯甲酰(BP)浓度达到3.84 g/lit时,接枝率显著提高,接枝率随引发剂浓度的增加而降低。PET的预膨胀导致其吸附扩散性能的变化,有利于接枝程度的增加。经抗生素处理的接枝织物对革兰氏阳性和革兰氏阴性微生物均有抗菌作用。利用红外光谱和扫描电镜对涤纶接枝织物进行了表征。
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Surface Modification of PET Fabric by Graft Copolymerization with Acrylic Acid and Its Antibacterial Properties.

Graft copolymerization of acrylic acid (AA) onto Poly(ethylene terephthalate) (PET) fabrics with the aid of benzoyl peroxide was carried out. The effect of polymerization parameters on the graft yield was studied. Percent grafting was enhanced significantly by increasing benzoyl peroxide (BP) concentrations up to 3.84 g/lit and then decreased upon further increase in initiator concentration. Preswelling of PET leads to changes in its sorption-diffusion properties and favors an increase in the degree of grafting. The antibiotics treated grafted fabrics showed antibacterial properties towards gram-positive and gram-negative microorganisms. FTIR and SEM were used to characterize AA-grafted polyester fabrics.

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