Maksym Dekhtiarenko , György Szalóki , Vincent Croué , Jennifer Bou Zeid , David Canevet , Magali Allain , Vincent Carré , Frédéric Aubriet , Zoia Voitenko , Marc Sallé , Sébastien Goeb
{"title":"利用基于exTTF的自组装笼的空腔尺寸†","authors":"Maksym Dekhtiarenko , György Szalóki , Vincent Croué , Jennifer Bou Zeid , David Canevet , Magali Allain , Vincent Carré , Frédéric Aubriet , Zoia Voitenko , Marc Sallé , Sébastien Goeb","doi":"10.1039/d3qo00214d","DOIUrl":null,"url":null,"abstract":"<div><p>M<sub>4</sub>L<sub>2</sub> metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.</p></div>","PeriodicalId":94379,"journal":{"name":"Organic chemistry frontiers : an international journal of organic chemistry","volume":"10 7","pages":"Pages 1803-1810"},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Playing with the cavity size of exTTF-based self-assembled cages†\",\"authors\":\"Maksym Dekhtiarenko , György Szalóki , Vincent Croué , Jennifer Bou Zeid , David Canevet , Magali Allain , Vincent Carré , Frédéric Aubriet , Zoia Voitenko , Marc Sallé , Sébastien Goeb\",\"doi\":\"10.1039/d3qo00214d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>M<sub>4</sub>L<sub>2</sub> metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.</p></div>\",\"PeriodicalId\":94379,\"journal\":{\"name\":\"Organic chemistry frontiers : an international journal of organic chemistry\",\"volume\":\"10 7\",\"pages\":\"Pages 1803-1810\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic chemistry frontiers : an international journal of organic chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2052411023006004\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic chemistry frontiers : an international journal of organic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2052411023006004","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Playing with the cavity size of exTTF-based self-assembled cages†
M4L2 metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.
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