{"title":"气体的导热性。3在1 × 105 ~ 2.5 × 107帕斯卡压力下,0 ~ 75℃范围内氩、氦、氮的热导率的一些数值。","authors":"Leslie A Guildner","doi":"10.6028/jres.079A.005","DOIUrl":null,"url":null,"abstract":"<p><p>Accurate measurements of the thermal conductivities of Ar and He agree with the theoretical value of 2.5 <i>ϕηc</i> <sub><i>v</i></sub> (<i>η</i> = viscosity, <i>c</i> <sub><i>v</i></sub> = specific heat capacity at constant volume <i>ϕ</i> is a number slightly greater than 1 depending upon the intermolecular potential). Measurements of the thermal conductivities of N<sub>2</sub> at 9.6 and 75 °C as a function of pressure up to 2.53 × 10<sup>7</sup> Pa help to appraise the validity of other measurements of the thermal conductivities of dense gases. The excess conductivity of nitrogen (the additional conductivity resulting from pressure) is shown to be a function of only the density of the nitrogen from 0 to 700 °C and pressures up to 1.3 × 10<sup>8</sup> Pa.</p>","PeriodicalId":17018,"journal":{"name":"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry","volume":"79A 2","pages":"407-413"},"PeriodicalIF":0.0000,"publicationDate":"1975-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6565413/pdf/jres-79A-407.pdf","citationCount":"8","resultStr":"{\"title\":\"Thermal Conductivity of Gases. III. Some Values of the Thermal Conductivities of Argon, Helium, and Nitrogen from 0 °C to 75 °C at Pressures of 1 × 10<sup>5</sup> to 2.5 × 10<sup>7</sup> Pascals.\",\"authors\":\"Leslie A Guildner\",\"doi\":\"10.6028/jres.079A.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Accurate measurements of the thermal conductivities of Ar and He agree with the theoretical value of 2.5 <i>ϕηc</i> <sub><i>v</i></sub> (<i>η</i> = viscosity, <i>c</i> <sub><i>v</i></sub> = specific heat capacity at constant volume <i>ϕ</i> is a number slightly greater than 1 depending upon the intermolecular potential). Measurements of the thermal conductivities of N<sub>2</sub> at 9.6 and 75 °C as a function of pressure up to 2.53 × 10<sup>7</sup> Pa help to appraise the validity of other measurements of the thermal conductivities of dense gases. The excess conductivity of nitrogen (the additional conductivity resulting from pressure) is shown to be a function of only the density of the nitrogen from 0 to 700 °C and pressures up to 1.3 × 10<sup>8</sup> Pa.</p>\",\"PeriodicalId\":17018,\"journal\":{\"name\":\"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry\",\"volume\":\"79A 2\",\"pages\":\"407-413\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1975-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6565413/pdf/jres-79A-407.pdf\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.6028/jres.079A.005\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6028/jres.079A.005","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
摘要
对Ar和He的热导率的精确测量与2.5 μ d ηc v的理论值一致(η =粘度,c v =定容时的比热容φ是一个略大于1的数字,取决于分子间势)。氮气在9.6℃和75℃下的热导率随压力达2.53 × 107 Pa的函数的测量有助于评估致密气体热导率的其他测量的有效性。氮气的超导电性(由压力产生的额外导电性)显示为仅在0至700°C和高达1.3 × 108 Pa的压力下氮气密度的函数。
Thermal Conductivity of Gases. III. Some Values of the Thermal Conductivities of Argon, Helium, and Nitrogen from 0 °C to 75 °C at Pressures of 1 × 105 to 2.5 × 107 Pascals.
Accurate measurements of the thermal conductivities of Ar and He agree with the theoretical value of 2.5 ϕηcv (η = viscosity, cv = specific heat capacity at constant volume ϕ is a number slightly greater than 1 depending upon the intermolecular potential). Measurements of the thermal conductivities of N2 at 9.6 and 75 °C as a function of pressure up to 2.53 × 107 Pa help to appraise the validity of other measurements of the thermal conductivities of dense gases. The excess conductivity of nitrogen (the additional conductivity resulting from pressure) is shown to be a function of only the density of the nitrogen from 0 to 700 °C and pressures up to 1.3 × 108 Pa.