{"title":"0 至 100 °C 范围内水的蒸汽压公式。A 修订版。","authors":"Arnold Wexler","doi":"10.6028/jres.080A.071","DOIUrl":null,"url":null,"abstract":"<p><p>In 1971 Wexler and Greenspan published a formulation for the vapor pressure of water encompassing the temperature range 0 to 100 °C. In this paper a revision is made of that earlier formulation to make it consistent with the definitive experimental value of the vapor pressure of water at its triple point recently obtained by Guildner, Johnson, and Jones. The two formulations are essentially identical at temperatures from 25 to 100 °C. For temperatures below 25 °C the new formulation predicts values that are higher than the 1971 formulation. At the triple point, the vapor pressure given by the new formulation is 611.657 Pa whereas the value given by the 1971 formulation is 611.196 Pa. A table is given of the vapor pressure as a function of temperature at 0.1-deg intervals over the range 0 to 100 °C on the International Practical Temperature Scale of 1968, together with values of the temperature derivative at 1-deg intervals.</p>","PeriodicalId":17018,"journal":{"name":"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry","volume":"80A 5-6","pages":"775-785"},"PeriodicalIF":0.0000,"publicationDate":"1976-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5312760/pdf/","citationCount":"0","resultStr":"{\"title\":\"Vapor Pressure Formulation for Water in Range 0 to 100 °C. A Revision.\",\"authors\":\"Arnold Wexler\",\"doi\":\"10.6028/jres.080A.071\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In 1971 Wexler and Greenspan published a formulation for the vapor pressure of water encompassing the temperature range 0 to 100 °C. In this paper a revision is made of that earlier formulation to make it consistent with the definitive experimental value of the vapor pressure of water at its triple point recently obtained by Guildner, Johnson, and Jones. The two formulations are essentially identical at temperatures from 25 to 100 °C. For temperatures below 25 °C the new formulation predicts values that are higher than the 1971 formulation. At the triple point, the vapor pressure given by the new formulation is 611.657 Pa whereas the value given by the 1971 formulation is 611.196 Pa. A table is given of the vapor pressure as a function of temperature at 0.1-deg intervals over the range 0 to 100 °C on the International Practical Temperature Scale of 1968, together with values of the temperature derivative at 1-deg intervals.</p>\",\"PeriodicalId\":17018,\"journal\":{\"name\":\"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry\",\"volume\":\"80A 5-6\",\"pages\":\"775-785\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1976-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5312760/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.6028/jres.080A.071\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"1976/10/1 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6028/jres.080A.071","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"1976/10/1 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
1971 年,韦克斯勒和格林斯潘发表了水蒸气压的计算公式,涵盖了 0 到 100 °C 的温度范围。本文对之前的公式进行了修订,使其与 Guildner、Johnson 和 Jones 最近获得的水在三相点时的蒸气压的最终实验值保持一致。这两个公式在 25 至 100 °C 的温度范围内基本相同。在温度低于 25 °C 时,新公式的预测值高于 1971 年的公式。在三相点上,新配方给出的蒸气压为 611.657 Pa,而 1971 年配方给出的值为 611.196 Pa。
Vapor Pressure Formulation for Water in Range 0 to 100 °C. A Revision.
In 1971 Wexler and Greenspan published a formulation for the vapor pressure of water encompassing the temperature range 0 to 100 °C. In this paper a revision is made of that earlier formulation to make it consistent with the definitive experimental value of the vapor pressure of water at its triple point recently obtained by Guildner, Johnson, and Jones. The two formulations are essentially identical at temperatures from 25 to 100 °C. For temperatures below 25 °C the new formulation predicts values that are higher than the 1971 formulation. At the triple point, the vapor pressure given by the new formulation is 611.657 Pa whereas the value given by the 1971 formulation is 611.196 Pa. A table is given of the vapor pressure as a function of temperature at 0.1-deg intervals over the range 0 to 100 °C on the International Practical Temperature Scale of 1968, together with values of the temperature derivative at 1-deg intervals.