Zhengjie Yao, Zhenwei Zhang, Jiali Li, Ji Jia, Si Ma, Yongfeng Zhi, Hong Xia and Xiaoming Liu
{"title":"通过炔-炔交叉偶联反应形成的全π共轭二炔连接共价有机骨架","authors":"Zhengjie Yao, Zhenwei Zhang, Jiali Li, Ji Jia, Si Ma, Yongfeng Zhi, Hong Xia and Xiaoming Liu","doi":"10.1039/D1QM01322J","DOIUrl":null,"url":null,"abstract":"<p >A novel diyne-linked porphyrin-based COF was constructed through palladium-catalyzed alkyne–alkyne coupling for the first time. The new material features inherent porosity, moderate crystallinity, excellent durability, full π-conjugation, and can effectively induce the borylation of arylamines under visible-light illumination, and display broad substrate adaptability and good recyclability.</p>","PeriodicalId":86,"journal":{"name":"Materials Chemistry Frontiers","volume":null,"pages":null},"PeriodicalIF":6.0000,"publicationDate":"2021-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Fully π-conjugated, diyne-linked covalent organic frameworks formed via alkyne–alkyne cross-coupling reaction†\",\"authors\":\"Zhengjie Yao, Zhenwei Zhang, Jiali Li, Ji Jia, Si Ma, Yongfeng Zhi, Hong Xia and Xiaoming Liu\",\"doi\":\"10.1039/D1QM01322J\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A novel diyne-linked porphyrin-based COF was constructed through palladium-catalyzed alkyne–alkyne coupling for the first time. The new material features inherent porosity, moderate crystallinity, excellent durability, full π-conjugation, and can effectively induce the borylation of arylamines under visible-light illumination, and display broad substrate adaptability and good recyclability.</p>\",\"PeriodicalId\":86,\"journal\":{\"name\":\"Materials Chemistry Frontiers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.0000,\"publicationDate\":\"2021-12-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Chemistry Frontiers\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2022/qm/d1qm01322j\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry Frontiers","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2022/qm/d1qm01322j","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Fully π-conjugated, diyne-linked covalent organic frameworks formed via alkyne–alkyne cross-coupling reaction†
A novel diyne-linked porphyrin-based COF was constructed through palladium-catalyzed alkyne–alkyne coupling for the first time. The new material features inherent porosity, moderate crystallinity, excellent durability, full π-conjugation, and can effectively induce the borylation of arylamines under visible-light illumination, and display broad substrate adaptability and good recyclability.
期刊介绍:
Materials Chemistry Frontiers focuses on the synthesis and chemistry of exciting new materials, and the development of improved fabrication techniques. Characterisation and fundamental studies that are of broad appeal are also welcome.
This is the ideal home for studies of a significant nature that further the development of organic, inorganic, composite and nano-materials.