W J Boettinger, D E Newbury, N W M Ritchie, M E Williams, U R Kattner, E A Lass, K-W Moon, M B Katz, J H Perepezko
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Differential thermal analysis (DTA) and microstructural and microprobe measurements of DTA and as-cast Ni-Re alloys with compositions between 0.20 and 0.44 mass fraction Re provide information to resolve differences in previously published Ni-Re phase diagrams. This investigation determines that the peritectic invariant between liquid, Re-rich hexagonal close packed and Ni-rich face center cubic phases, L + HCP → FCC, occurs at 1561.1 °C ± 3.4 °C (1σ) with compositions of liquid, FCC and HCP phases of 0.283 ± 0.036, 0.436 ± 0.026, and 0.828 ± 0.037 mass fraction Re, respectively. Analysis of the microsegregation in FCC alloys yields a partition coefficient for solidification, k = 1.54 ± 0.09 (mass frac./mass frac.). A small deviation from Scheil behavior due to dendrite tip kinetics is documented in as-cast samples. No evidence of an intermetallic phase is observed.
期刊介绍：
Metallurgical and Materials Transactions A focuses on the latest research in all aspects of physical metallurgy and materials science. It explores relationships among processing, structure, and properties of materials; publishes critically reviewed, original research of archival significance.
The journal address the main topics of alloy phases; transformations; transport phenomena; mechanical behavior; physical chemistry; environment; welding & joining; surface treatment; electronic, magnetic & optical material; solidification; materials processing; composite materials; biomaterials; and light metals. MMTA publishes Technical Publications, Communications, Symposia, and more.
Published with ASM International, The Materials Information Society and The Minerals, Metals & Materials Society (TMS)
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