一种新型耐热Cu(II)配位聚合物:光催化活性及其在糖尿病中的应用价值。

IF 1.8 4区 化学 Q3 POLYMER SCIENCE Designed Monomers and Polymers Pub Date : 2021-05-07 DOI:10.1080/15685551.2021.1921341
Chen-Lu Jin, Shao-Jun Fang, Li Yu, Zhen-Shan Guo
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引用次数: 4

摘要

在溶剂热条件下,将HL和4,4'-bipy的混合配体与Cu(ClO4)2·6H2O反应,成功制备了一种由[Cu2(L)2(4,4'-bipy)2]n·2n (ClO4) (1,hl = 4-甲基-L-苯丙氨酸,4,4'-bipy = 4,4'-联吡啶)组成的Cu(II)配位聚合物。所合成的化合物不仅在275℃前具有较高的热稳定性,而且在紫外光照射下对甲基蓝溶液的降解具有优异的光催化活性。进一步测定了该化合物对糖尿病的治疗活性,并对其作用机制进行了研究。本研究还对所合成化合物的细胞毒性或溶血毒性(HC50)进行了评价。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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A new thermostable Cu(II) coordination polymer: photocatalytic activity and application values on diabetes.

A Cu(II) coordination polymer with the composition of [Cu2(L)2(4,4'-bipy)2]n·2 n(ClO4) (1, HL = 4-methyl-L-phenylalanine and 4,4'-bipy is 4,4'-bipyridine), was successfully obtained by the reaction of the mixed ligand of HL and 4,4'-bipy with Cu(ClO4)2 · 6H2O under solvothermal condition. The as-synthesized compound not only has high thermal stability until 275°C but also excellent photocatalytic activity for the methyl blue solution degradation under the irradiation of ultraviolet light. Furthermore, the compound's treatment activity on the diabetes was determined and its relevant mechanism was also studied. The cytotoxicity or hemolysis toxicity (HC50) of the synthesized compound was also evaluated in this research.

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来源期刊
Designed Monomers and Polymers
Designed Monomers and Polymers 化学-高分子科学
CiteScore
3.30
自引率
0.00%
发文量
28
审稿时长
2.1 months
期刊介绍: Designed Monomers and Polymers ( DMP) publishes prompt peer-reviewed papers and short topical reviews on all areas of macromolecular design and applications. Emphasis is placed on the preparations of new monomers, including characterization and applications. Experiments should be presented in sufficient detail (including specific observations, precautionary notes, use of new materials, techniques, and their possible problems) that they could be reproduced by any researcher wishing to repeat the work. The journal also includes macromolecular design of polymeric materials (such as polymeric biomaterials, biomedical polymers, etc.) with medical applications. DMP provides an interface between organic and polymer chemistries and aims to bridge the gap between monomer synthesis and the design of new polymers. Submssions are invited in the areas including, but not limited to: -macromolecular science, initiators, macroinitiators for macromolecular design -kinetics, mechanism and modelling aspects of polymerization -new methods of synthesis of known monomers -new monomers (must show evidence for polymerization, e.g. polycondensation, sequential combination, oxidative coupling, radiation, plasma polymerization) -functional prepolymers of various architectures such as hyperbranched polymers, telechelic polymers, macromonomers, or dendrimers -new polymeric materials with biomedical applications
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