Shogo Taguchi, Yasuaki Tachibana, Yuta Kimura, Takuji Yamamoto, Hiroshi Umakoshi
{"title":"油酸/CHAPSO小柱制备不同聚集体的简单稀释法。","authors":"Shogo Taguchi, Yasuaki Tachibana, Yuta Kimura, Takuji Yamamoto, Hiroshi Umakoshi","doi":"10.1166/jnn.2021.19501","DOIUrl":null,"url":null,"abstract":"<p><p>We evaluated the effect of dilution on both the size and packing density of aggregates prepared from a fatty acid (oleic acid, OA)/detergent (3-[(3-cholamidopropyl)dimethylammonio]-2-hydroxypropane sulfonate (CHAPSO)) bicelle as a parent for functional membrane materials. The sizes of the aggregates formed at different molar ratios, <i>X</i><sub>OA</sub>(= [OA]/([OA]+[CHAPSO])), of 0.3 and 0.7 and their parent bicelles were measured by dynamic light scattering and transmission electron microscopy; their packing density was evaluated by deconvolution of the fluorescence spectrum, where Laurdan molecules were used as a probe. The experimental results showed that the bicelles formed aggregates upon dilution because of the hydration of CHAPSO. The packing density of the nano-ordered aggregate formed at <i>X</i><sub>OA</sub> = 0.3 was much greater than that of the aggregate formed at <i>X</i><sub>OA</sub> = 0.7, implying the formation of an ordered aggregate under the condition of <i>X</i><sub>OA</sub> = 0.3.</p>","PeriodicalId":16417,"journal":{"name":"Journal of nanoscience and nanotechnology","volume":"21 12","pages":"5993-5999"},"PeriodicalIF":0.0000,"publicationDate":"2021-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A Simple Dilution Method for Preparation of Different Aggregates from Oleic Acid/CHAPSO Bicelles.\",\"authors\":\"Shogo Taguchi, Yasuaki Tachibana, Yuta Kimura, Takuji Yamamoto, Hiroshi Umakoshi\",\"doi\":\"10.1166/jnn.2021.19501\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>We evaluated the effect of dilution on both the size and packing density of aggregates prepared from a fatty acid (oleic acid, OA)/detergent (3-[(3-cholamidopropyl)dimethylammonio]-2-hydroxypropane sulfonate (CHAPSO)) bicelle as a parent for functional membrane materials. The sizes of the aggregates formed at different molar ratios, <i>X</i><sub>OA</sub>(= [OA]/([OA]+[CHAPSO])), of 0.3 and 0.7 and their parent bicelles were measured by dynamic light scattering and transmission electron microscopy; their packing density was evaluated by deconvolution of the fluorescence spectrum, where Laurdan molecules were used as a probe. The experimental results showed that the bicelles formed aggregates upon dilution because of the hydration of CHAPSO. The packing density of the nano-ordered aggregate formed at <i>X</i><sub>OA</sub> = 0.3 was much greater than that of the aggregate formed at <i>X</i><sub>OA</sub> = 0.7, implying the formation of an ordered aggregate under the condition of <i>X</i><sub>OA</sub> = 0.3.</p>\",\"PeriodicalId\":16417,\"journal\":{\"name\":\"Journal of nanoscience and nanotechnology\",\"volume\":\"21 12\",\"pages\":\"5993-5999\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of nanoscience and nanotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1166/jnn.2021.19501\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of nanoscience and nanotechnology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1166/jnn.2021.19501","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Simple Dilution Method for Preparation of Different Aggregates from Oleic Acid/CHAPSO Bicelles.
We evaluated the effect of dilution on both the size and packing density of aggregates prepared from a fatty acid (oleic acid, OA)/detergent (3-[(3-cholamidopropyl)dimethylammonio]-2-hydroxypropane sulfonate (CHAPSO)) bicelle as a parent for functional membrane materials. The sizes of the aggregates formed at different molar ratios, XOA(= [OA]/([OA]+[CHAPSO])), of 0.3 and 0.7 and their parent bicelles were measured by dynamic light scattering and transmission electron microscopy; their packing density was evaluated by deconvolution of the fluorescence spectrum, where Laurdan molecules were used as a probe. The experimental results showed that the bicelles formed aggregates upon dilution because of the hydration of CHAPSO. The packing density of the nano-ordered aggregate formed at XOA = 0.3 was much greater than that of the aggregate formed at XOA = 0.7, implying the formation of an ordered aggregate under the condition of XOA = 0.3.
期刊介绍：
JNN is a multidisciplinary peer-reviewed journal covering fundamental and applied research in all disciplines of science, engineering and medicine. JNN publishes all aspects of nanoscale science and technology dealing with materials synthesis, processing, nanofabrication, nanoprobes, spectroscopy, properties, biological systems, nanostructures, theory and computation, nanoelectronics, nano-optics, nano-mechanics, nanodevices, nanobiotechnology, nanomedicine, nanotoxicology.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
