Automated High-Temperature PVT Apparatus With Data for Propane.

An apparatus is described which can be used for PVT and compressibility measurements on supercritical fluids from near room temperature to 600 °C and pressures to 35 MPa. Two separate experimental techniques are employed to obtain PVT data over a broad range of the state surface. Burnett expansions are performed to generate compressibility factor (or equivalently density) data along a well-behaved supercritical isotherm. A series of isochoric measurements is then made to extend the temperature range. Densities assigned to the isochores are determined from their intersection with the previously measured Burnett isotherm or gravimetrically. A computer is used for experimental control and for data logging. Isochoric measurements lasting several days can be performed routinely and without operator attention. The apparatus has been tested on propane to a temperature of 325 °C. The density data, estimated accurate to ±0.1 percent, are in excellent agreement with other existing data.