Mohammed C. Al-Kinany, Saud A. Al-Drees, Hamid A. Al -Megren, Saeed M. Alshihri, Eyad A. Alghilan, Feras A. Al-Shehri, Abdulmohsin S. Al-Hamdan, Abdullah J. Alghamdi, Sami D. Al-Dress
{"title":"轻烯烃在h-沸石- y负载型磷酸上聚合制备高质量燃料馏分","authors":"Mohammed C. Al-Kinany, Saud A. Al-Drees, Hamid A. Al -Megren, Saeed M. Alshihri, Eyad A. Alghilan, Feras A. Al-Shehri, Abdulmohsin S. Al-Hamdan, Abdullah J. Alghamdi, Sami D. Al-Dress","doi":"10.1007/s13203-019-0225-1","DOIUrl":null,"url":null,"abstract":"<p>Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3?mol</sub> ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100?°C under atmospheric pressure with a space velocity (WHSV) of 176?h<sup>?1</sup>.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C<span>\n <sup>=</sup><sub>8</sub>\n \n </span> isomers is about 65%, and a flow rate of isobutene 5.0?ml/min. and temperature 50?°C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125?Pa.</p>","PeriodicalId":472,"journal":{"name":"Applied Petrochemical Research","volume":null,"pages":null},"PeriodicalIF":0.1250,"publicationDate":"2019-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13203-019-0225-1","citationCount":"11","resultStr":"{\"title\":\"High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y\",\"authors\":\"Mohammed C. Al-Kinany, Saud A. Al-Drees, Hamid A. Al -Megren, Saeed M. Alshihri, Eyad A. Alghilan, Feras A. Al-Shehri, Abdulmohsin S. Al-Hamdan, Abdullah J. Alghamdi, Sami D. Al-Dress\",\"doi\":\"10.1007/s13203-019-0225-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3?mol</sub> ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100?°C under atmospheric pressure with a space velocity (WHSV) of 176?h<sup>?1</sup>.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C<span>\\n <sup>=</sup><sub>8</sub>\\n \\n </span> isomers is about 65%, and a flow rate of isobutene 5.0?ml/min. and temperature 50?°C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125?Pa.</p>\",\"PeriodicalId\":472,\"journal\":{\"name\":\"Applied Petrochemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.1250,\"publicationDate\":\"2019-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s13203-019-0225-1\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Petrochemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13203-019-0225-1\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Petrochemical Research","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1007/s13203-019-0225-1","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y
Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO2/Al2O3?mol ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100?°C under atmospheric pressure with a space velocity (WHSV) of 176?h?1.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C=8 isomers is about 65%, and a flow rate of isobutene 5.0?ml/min. and temperature 50?°C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125?Pa.
期刊介绍：
Applied Petrochemical Research is a quarterly Open Access journal supported by King Abdulaziz City for Science and Technology and all the manuscripts are single-blind peer-reviewed for scientific quality and acceptance. The article-processing charge (APC) for all authors is covered by KACST. Publication of original applied research on all aspects of the petrochemical industry focusing on new and smart technologies that allow the production of value-added end products in a cost-effective way. Topics of interest include: • Review of Petrochemical Processes • Reaction Engineering • Design • Catalysis • Pilot Plant and Production Studies • Synthesis As Applied to any of the following aspects of Petrochemical Research: -Feedstock Petrochemicals: Ethylene Production, Propylene Production, Butylene Production, Aromatics Production (Benzene, Toluene, Xylene etc...), Oxygenate Production (Methanol, Ethanol, Propanol etc…), Paraffins and Waxes. -Petrochemical Refining Processes: Cracking (Steam Cracking, Hydrocracking, Fluid Catalytic Cracking), Reforming and Aromatisation, Isomerisation Processes, Dimerization and Polymerization, Aromatic Alkylation, Oxidation Processes, Hydrogenation and Dehydrogenation. -Products: Polymers and Plastics, Lubricants, Speciality and Fine Chemicals (Adhesives, Fragrances, Flavours etc...), Fibres, Pharmaceuticals.
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