Joshua Rushlow, Andrei V Astashkin, Daniel R Albert, Edward Rajaseelan
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引用次数: 0
摘要
标题化合物[Ir(C8H12)(C6H11N3)(C18H33P)]BF4-CH2Cl2 是一种基于三唑的 N-杂环碳化铱（I）阳离子络合物，带有一个四氟硼酸对位离子，每个式单元结晶出一个二氯甲烷溶剂分子。阳离子络合物中的 IrI 原子具有扭曲的方形平面配位环境，该环境由双齿环辛烷-1,5-二烯（COD）配体、N-杂环碳烯和三环己基膦烷配体确定。该复合物结晶于一个以 C 为中心的单斜晶胞中，并具有非常多的 8 个配方单元。
The title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra-fluorido-borate counter-anion, crystallizes with one di-chloro-methane solvent mol-ecule per formula unit. The IrI atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tri-cyclo-hexyl-phosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units.
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