{"title":"反式-羰基-氯基-双-(三乙基膦-κP)四氟硼酸铂(II)。","authors":"Peter W R Corfield","doi":"10.1107/S2414314622006071","DOIUrl":null,"url":null,"abstract":"<p><p>The chemical formulation of the title compound was established as <i>trans</i>-[PtCl{P(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>(CO)}BF<sub>4</sub> by single-crystal X-ray analysis, in contrast to the five-coordinate tetra-fluoro-ethyl-ene complex that had been anti-cipated. The compound had been prepared by reaction of <i>trans</i>-PtHCl(P(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>)<sub>2</sub> with C<sub>2</sub>F<sub>4</sub> in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF<sub>4</sub> <sup>-</sup> anions are linked by C-H⋯F and C-H⋯O inter-actions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967.</p>","PeriodicalId":14692,"journal":{"name":"IUCrData","volume":"7 Pt 6","pages":"x220607"},"PeriodicalIF":0.0000,"publicationDate":"2022-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/pdf/","citationCount":"0","resultStr":"{\"title\":\"<i>trans</i>-Carbonyl-chlorido-bis-(tri-ethyl-phosphane-κ<i>P</i>)platinum(II) tetra-fluorido-borate.\",\"authors\":\"Peter W R Corfield\",\"doi\":\"10.1107/S2414314622006071\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The chemical formulation of the title compound was established as <i>trans</i>-[PtCl{P(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>(CO)}BF<sub>4</sub> by single-crystal X-ray analysis, in contrast to the five-coordinate tetra-fluoro-ethyl-ene complex that had been anti-cipated. The compound had been prepared by reaction of <i>trans</i>-PtHCl(P(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>)<sub>2</sub> with C<sub>2</sub>F<sub>4</sub> in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF<sub>4</sub> <sup>-</sup> anions are linked by C-H⋯F and C-H⋯O inter-actions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967.</p>\",\"PeriodicalId\":14692,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"7 Pt 6\",\"pages\":\"x220607\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462037/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2414314622006071\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2022/6/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314622006071","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2022/6/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
The chemical formulation of the title compound was established as trans-[PtCl{P(C2H5)3(CO)}BF4 by single-crystal X-ray analysis, in contrast to the five-coordinate tetra-fluoro-ethyl-ene complex that had been anti-cipated. The compound had been prepared by reaction of trans-PtHCl(P(C2H5)3)2 with C2F4 in the absence of air, and the presence of the carbonyl group was not suspected. The square-planar cations and BF4- anions are linked by C-H⋯F and C-H⋯O inter-actions into thick wavy (010) sheets. The present crystal-structure refinement is based on the original intensity data recorded in 1967.
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