喷雾热解法分析ZnO对碳纳米管的影响

A. Ayeshamariam, D. Saravanakkumar, M. Kashif, S. Sivaranjani, B. Ravikumar
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引用次数: 15

摘要

以乙酸锌为原料,在铜板、甘氨酸和糖溶液的辅助下制备了ZnO/CNT纳米复合材料。这两种材料之间的结合行为可能会产生在电子和光电子领域具有广泛应用的先进材料。采用简单的香水喷雾热解方法在铜基体上成功制备了ZnO-CNT纳米结构。本文尝试探索了这种方法形成ZnO-CNT纳米晶体的可能生长机理,并对其光学性能进行了验证。采用扫描电镜(SEM)、透射电镜(TEM)和Cu Kα辐射x射线衍射(XRD)对合成的ZnO-CNT纳米结构进行了表征。对ZnO包覆碳纳米管的形貌研究表明,单壁石墨片的内部结构和碳纳米管的直径没有明显变化,但ZnO似乎在纳米管表面形成了一层薄膜状的单晶颗粒。380?激发光致发光(PL)测量Nm在室温下进行。由于碳纳米管的长度较长,在基础流体中的扩散迁移率较低,因此碳纳米管易于缠绕和团聚。ZnO/CNT复合材料具有较低的迁移率,在200℃时达到较高的线性灵敏度。样品的发光以结构良好的紫外波段发光为主,几乎没有观察到深能级发光,表明所制备的结构具有很高的光学质量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Analysis on the effect of ZnO on Carbon nanotube by spray pyrolysis method

ZnO/CNT nanocomposites were prepared using Zinc acetate source materials and with the assistance of copper plate, glycine and sugar solution. The combined behavior between these two materials may give rise to the production of advanced materials with a wide range of applications in electronics and optoelectronics.

The ZnO-CNT nanostructures are successfully prepared by simple perfume spray pyrolysis method on copper substrate. The possible growth mechanism of ZnO-CNT nanocrystals formation by this method has been tried to explore the sensor and optical properties has been demonstrated.

The as-synthesized ZnO-CNT nanostructures were characterized using the scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD) pattern measured with Cu Kα radiation. Studies of the morphologies of the ZnO-coated CNTs revealed no significant change in the internal structures single walled graphite sheets and the diameters of the CNTs, but the ZnO appeared to form a layer of thinfilm single crystalline particles attaching to the surface of the nanotubes. The photoluminescence (PL) measurements excited by the 380?nm were done at room temperature. CNTs are easy to be entangled and agglomerate due to their long length and low diffusive mobility in base fluids.

The lower mobility was found to occur for the ZnO/CNT composite where a linear sensitivity behavior was measured and it reaches high at the temperature of 200 °C. The samples luminescence is dominated by well-structured ultraviolet band emission and almost no deep level emission was observed, revealing a high optical quality of the produced structures.

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