纳米结构钛的耐腐蚀性能

H. Garbacz , M. Pisarek , K.J. Kurzydłowski
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引用次数: 93

摘要

本文报道了纯纳米级2级钛经静液挤压后的耐腐蚀性能研究结果。所检测样品的晶粒尺寸在90 nm以下。采用原子发射光谱(AES)和氩离子溅射相结合的表面分析技术,研究了纳米钛表面形成的氧化物的化学成分和厚度。结果表明,钛基体的晶粒尺寸对钛表面形成的氧化层厚度没有影响。静流体挤压前后钛样品表面氧化膜厚度约为6 nm。在NaCl溶液中进行的测试表明,纳米钛的耐腐蚀性略低于微米尺寸的钛。
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Corrosion resistance of nanostructured titanium

The present work reports results of studies of corrosion resistance of pure nano-Ti-Grade 2 after hydrostatic extrusion. The grain size of the examined samples was below 90 nm. Surface analytical technique including AES combined with Ar+ ion sputtering, were used to investigate the chemical composition and thicknesses of the oxides formed on nano-Ti. It has been found that the grain size of the titanium substrate did not influence the thickness of oxide formed on the titanium. The thickness of the oxide observed on the titanium samples before and after hydrostatic extrusion was about 6 nm. Tests carried out in a NaCl solution revealed a slightly lower corrosion resistance of nano-Ti in comparison with the titanium with micrometric grain size.

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