透明导电衬底对电化学生长CdSe和CdSe: Fe薄膜物理、化学和光学性能的影响

IF 0.7 4区 材料科学 Q4 ELECTROCHEMISTRY Journal of New Materials For Electrochemical Systems Pub Date : 2022-06-10 DOI:10.14447/jnmes.v25i2.a03
Sethuramachandran Thanikaikarasan, R. Perumal, R. Kanimozhi, M. Saravannan, P. S. Suja Ponmini
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引用次数: 0

摘要

II–VI族半导体因其在太阳能电池、太阳能选择性涂层和光电器件等行业中的广泛应用而被许多研究人员视为有趣的候选者。镉的硫族化合物由于其重要的结构特征、膜组成、电子和光学性质而受到广泛关注。采用低成本、低温电化学沉积技术在透明导电基底上制备了硒化镉和掺铁硒化镉薄膜。X射线衍射技术已被用于识别沉积薄膜的晶体性质和结构特征。能量色散X射线分析方法已被用于找出沉积薄膜的化学计量性质。对沉积薄膜的晶粒尺寸、应变、位错密度等参数进行了估算。采用紫外-可见光谱法测定了沉积薄膜的光学性质。估计发现沉积的膜显示出在1.67和1.74eV之间的带隙值以及光学参数折射率和消光系数的值。
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Role of Transparent Nature Conducting Substrate on Physical, Chemical and Optical Properties of Electrochemically Grown CdSe and CdSe: Fe Thin Films
Semiconductors of II–VI group considered as interesting candidate for many researchers owing to its wide variety of applications in industries such as solar cells, solar selective coatings and optoelectronic devices. Chalcogenides of Cadmium received much attention due to its important structural feature, film composition, electronic and optical properties. The technique of low cost, low temperature electrochemical deposition has been employed to prepare Cadmium Selenide and Iron incorporated Cadmium Selenide thin films on transparent nature conducting substrates. The technique of X-ray diffraction has been used to identify crystalline nature and structural features of the deposited films. The method of Energy dispersive X-ray analysis has been used to find out the stoichiometric nature of the deposited films. The parameters viz., crystallite size, strain, dislocation density are estimated for the deposited films. The method of Ultraviolet-Visible spectroscopic measurements has been carried out to determine the optical properties of the deposited films. The deposited films found to exhibit band gap value in the range between 1.67 and 1.74 eV and the value of optical parameters refractive index and extinction coefficient, were estimated.
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来源期刊
Journal of New Materials For Electrochemical Systems
Journal of New Materials For Electrochemical Systems ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
1.90
自引率
0.00%
发文量
33
审稿时长
>12 weeks
期刊介绍: This international Journal is intended for the publication of original work, both analytical and experimental, and of reviews and commercial aspects related to the field of New Materials for Electrochemical Systems. The emphasis will be on research both of a fundamental and an applied nature in various aspects of the development of new materials in electrochemical systems.
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